Электрохимические конденсаторы

This work is dedicated to phosphoric acid esters working as solvents for lithium-ion and supercapacitor (SC) electrolyte. The electrical conductivity of electrolytes based on phosphoric acid esters, lithium salts, commonly used in lithium-ion batteries (LIB), and salts used in SC technology was measured. The thermodynamic stability of new electrolytes in comparison with other solvents used in chemical power sources technology was also estimated. It was shown that the thermodynamic stability of phosphoric acid ester increases in a homologous series.

DOI: https://doi.org/10.18500/1608-4039-2017-17-4-225-234

DOI: https://doi.org/10.18500/1608-4039-2017-17-4-173-224

The electrochemical characteristics of the electrode material based on activated “NORIT B Test EUR” carbon in 1 M sodium sulfate solution were evaluated by cyclic voltammetry, galvanostatic charge-discharge curves, and impedance spectroscopy. It is established that this material has low resistance, and the specific capacity of the electrode was 45 F/g.

A review of the current literature on hybrid supercapacitors (hybrid devices) in acid and alkaline electrolytes is presented.

The cyclic voltammetry was used to study the behavior of a symmetric supercapacitor with activated carbon cloth electrodes and a solution of an ionic liquid (C₈H₁₅N₂PF₆) in freon-22 as an electrolyte in the temperature range from ? 140 to + 130°C. The measurements were carried out in a special autoclave. At temperatures above 90°C, the supercapacitor exhibits purely capacitive behavior, whereas at the temperature lowering, the influence of resistance strongly increases.

The electrochemical characteristics of electrodes based on various fibrous carbon materials (manufactured by OOO NPTs Uvikom) for hybrid supercapacitors C/PbO₂ with an acid electrolyte have been investigated. It is shown that the highest values of the capacitive characteristics of the electrodes were obtained using carbon activated felt UVIS-AK-V-170, characterized by capacities up to 400 F/g.

In this paper, the electrochemical and electrophysical properties of protonated potassium polytitanate synthesized at pH values varying from 3.11 to 8.88 depending on the magnitude of the polarization voltage and the magnitude of the measured signal were studied by the method of impedance spectroscopy. The values of effective conductivity, relaxation times, frequency dependences of the loss tangent, and dielectric permittivity are determined.

4 августа 2019 г. исполнилось 90 лет известному в нашей стране специалисту в области электрохимической энергетики, выдающему организатору аккумуляторной промышленности Владимиру Никодимовичу Леонову.

13–14 февраля на площадке тольяттинского технопарка «Жигулевская долина» состоялась вторая Международная научно-техническая конференция «Battery Innovation 2020». Ее организаторами выступили Группа компаний «АКОМ» и научно-технический центр «Аккумулятор инноваций». Сегодня эту конференцию можно смело назвать традиционной ежегодной встречей научно-технической элиты в сфере производства и переработки химических источников тока.