For citation:
Chernyavina V. V., Berezhnaya A. G., Zhikhareva E. A. Activated Carbon “NORIT B Test EUR” as an Electrode Material for Supercapacitors. Electrochemical Energetics, 2018, vol. 18, iss. 4, pp. 192-?. DOI: 10.18500/1608-4039-2018-18-4-192-198, EDN: NWPJZQ
Activated Carbon “NORIT B Test EUR” as an Electrode Material for Supercapacitors
The electrochemical characteristics of the electrode material based on activated “NORIT B Test EUR” carbon in 1 M sodium sulfate solution were evaluated by cyclic voltammetry, galvanostatic charge-discharge curves, and impedance spectroscopy. It is established that this material has low resistance, and the specific capacity of the electrode was 45 F/g.
1. Kotz R., Carlen M. Principles and applications of electrochemical capacitors. Electrochim. Acta, 2000, vol. 45, pp. 2483–2498. DOI: https://doi.org/10.1016/S0013-4686(00)00354-6
2. Frackowiak E., Beguin F. Carbon materials for the electrochemical storage of energy in capacitors. Carbon, 2001, vol. 39, pp. 937–950.
3. Dubal D., Kim J., Kim Y., Holze R., Lokhande C., Kim W. Supercapacitors Based on Flexible Substrates. Energy Technology, 2014, vol. 2, no. 4, pp. 325–341. DOI: https://doi.org/10.1002/ente.201300144
4. Chmiola J., Yushin G., Dash R., Gogotsi Y. Effect of pore size and surface area of carb ide derived carbons on specific capacitance. J. Power Sources, 2006, vol. 158, no.1, pp. 765–772. DOI: https:// doi.org/10.1016/j.jpowsour.2005.09.008
5. Gubin S. P., Rychagov A. Yu., Chuprov P. N., Tkachev S. V., Kornilov D. Yu., Almazova A. S., Krasnova E. S., Voronov V. A. Supercapacitor based on electrochemically reduced graphene oxide. Electrochemical Energetics, 2015, vol. 15, no. 2, pp. 57–63 (in Russian).
6. Chepurnaya I. A., Logvinov S. A., Karushev M. P., Timonov A. M., Malev V. V. Modification of Supercapacitor Electrodes with Polymer Metallocomplexes: Methods and Results. Russ. J. Electrochem., 2012, vol. 48, no. 5, pp. 538–544. DOI: https:// doi.org/10.1134/S1023193512040040
7. Vol’fkovich Yu. M., Mikhalin A. A., Bograchev D. A., Sosenkin V. E. Carbon Electrodes with High Pseudocapacitance for Supercapacitors. Russ. J. Electrochem., 2012, vol. 48, no. 4, pp. 424–433. DOI: https://doi.org/10.1134/S1023193512030159
8. Song H., Hwang H., Lee К., Dao L. The effect of pore size distribution on the frequency dispersion of porous electrodes. Electrochim. Acta, 2000, vol. 45, no 14, pp. 2241–2257. DOI: https://doi.org/10.1016/S0013-4686(99)00436-3
9. Gryzlov L. Yu., Rychagov A. Yu., Skundin A. M., Kulova T. L. Study of activated ENER G2 P2-TYPE carbon as material for supercapacitors with nonaqueous electrolyte. Electrochemical Energetics, 2015, vol. 15, no. 4, pp. 160–166 (in Russian).
10. Lufrano F., Staiti P. Mesoporous carbon materials as electrodes for electrochemical supercapacitors. Int. J. Electrochem. Sci., 2010, vol. 5, pр. 903–916.
11. Qu D., Shi H. Studies of activated carbons used in double-layer capacitors. J. Power Sources, 1998, vol. 74, no.1, pp. 99–107. DOI: https://doi.org/10.1016/S0378-7753(98)00038-X
12. Tsay K.-C., Zhang L., Zhang J. Effects of electrode layer composition/thickness and electrolyte concentration on both specific capacitance and energy density of supercapacitor. Electrochim. Acta, 2012, vol. 60, pp. 428–436. DOI: https://doi.org/10.1016/j.electacta.2011.11.087
13. Burke A. Ultracapacitors: why, how, and where is the technology. J. Power Sources, 2000, vol. 91, no. 1, pp. 37–50. DOI: https://doi.org/10.1016/S0378-7753(00)00485-7
14. Ruiz V. Santamaria R., Granda M., Blanco C. Long-term cycling of carbon based supercapacitors in aqueous media. Electrochim. Acta, 2009, vol. 54, no. 19, pp. 4481–4486. DOI: https://doi.org/10.1016/j.electacta.2009.03.024
15. Wang Q., Yan J., Wang Y., Wei T., Zhang M., Jing X., Fan Z. Three-dimensional flower-like and hierarchical porous carbon materials as high-rate performance electrodes for supercapacitors. Carbon, 2014, vol. 67, pp. 119–127. DOI: https://doi.org/10.1016/j.carbon.2013.09.070
16. Wang J., Yang Y., Huang Z., Kang F. A high-performance asymmetric supercapacitor based on carbon and carbon–MnO2 nanofiber electrodes. Carbon, 2013, vol. 61, pp. 190–199. DOI: https://doi.org/10.1016/j.carbon.2013.04.084
17. Barcia O., D’Elia E., Frateur I. Mattos O., Pebere N., Tribollet B. Application of the impedance model of de Levie for the characterization of porous electrodes. Electrochim. Acta, 2002, vol. 47, pp. 2109–2116. DOI: https://doi.org/10.1016/S0013-4686(02)00081-6gh
18. Taberna P., Simon P., Fauvarque J. Electrochemical characteristics and impedance spectroscopy studies of carbon-carbon supercapacitors. Journal of the Electrochemical Society, 2003, vol. 150, no. 3, pp. 292–300. DOI: https://doi.org/10.1149/1.1543948
19. Kalluri R., Biener M., Suss M., Merrill M., Stadermann M., Santiago J., Baumann T., Biener J., Striolo A. Unraveling the potential and pore-size dependent capacitance of slit-shaped graphitic carbon pores in aqueous electrolytes. Physical Chemistry Chemical Physics, 2013, vol. 15, pp. 2309–2320. DOI: https://doi.org/10.1039/C2CP43361C
20. Zuliani J., Caguiat J., Kirk D., Jia C. Considerations for consistent characterization of electrochemical double-layer capacitor performance. J. Power Sources, 2015, vol. 290, pp. 136–143. DOI: https://doi.org/10.1016/j.jpowsour.2015.04.019
21. Hu C., Wang C. Nanostructures and capacitive characteristics of hydrous manganese oxide prepared by electrochemical deposition. Journal of the Electrochemical Society, 2003, vol. 150, no. 8, pp. 1079–1084. DOI: https://doi.org10.1149/1.1587725
22. Gamby J., Taberna P., Simon P., Fauvarque J., Chesneau M. Studies and characterisations of various activated carbons used for carbon/carbon supercapacitors. J. Power Sources, 2001, vol. 101, no. 1, pp. 109–116. DOI: https://doi.org/10.1016/S0378-7753(01)00707-8
23. Sugimoto W., Yokoshima K., Murakami Y., Takasu Y. Charge storage mechanism of nanostructured anhydrous and hydrous ruthenium-based oxides. Electrochim. Acta, 2006, vol. 52, pp.1742–1748.