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Electrochemical behavior of Li in the systems with PE based on polymers of chlorinated polyvinylchloride and polyvinylidene fluoride were investigated by the method of cyclic voltammetry and galvanostatic cycling. Potentiodynamic investigations have shown that on lithium electrode even in the systems with polymer electrolyte the high current densities up to 5 mA/cm² are realized. Influence of polymer electrolyte composition on the properties of the interface Li/electrolyte and rechargeable work of lithium electrode has been shown.

It was studied an influence of prior carbon treatment (temperature and gas conditions, mass content of waterproofing agent) on activity of platinum catalyst, synthesized on disperse carbon carrier. It was shown that characteristics of anodic processes depend on quantity of solid polymer electrolyte in catalytic composition. Optimal content of ion exchange polymer under varied degree of carbon carrier waterproofing (used for synthesis of platinum catalyst) is not equal.

There were investigated the self-discharge dynamics in two homogeneous groups («A» and «B») of the coin lithium cells ВR2325 on the basis of superstoichiometric fluorocarbon CF1.20, selected from the uniform experimental batch of 10000 pieces. The reason of two different groups («A» and «B») appearance through 3–6 months of storage is connected with the origin of hydrogen fluoride in cathodes of group «A» cells, which will be derivated at auto catalytic hydrolysis of C-F-bonds by a moisture tracers (0.1–0.5%).

Comparative characteristic of natural and synthesized iron disulfide has been carried out. Physical, chemical and macrostructure characteristics of pyrite powders have been shown. By the methods of cyclic Vtammetry the electrochemical properties of FeS₂ – based cathodes have been investigated in non-aqueous liquid (1М LiClO₄; PC+DME) and polymer (CPVC; 1М LiClO₄; PC) electrolytes.

Major trends in cathode active material development for lithium-ion batteries have been reviewed. Statistics on all publications in «Journal of Power Sources» (from 03.2006 till 04.2007) is summarized in order to point out that the main effort in secondary batteries development is concentrated on lithium-ion batteries, especially on positive electrode study. Based on these publications the main routes for LiCoO₂ modification as well as for novel materials research have been reviewed.

The effect of new kind of the separator, with the glassmat on the positive plate, which pressing the active mass, and new alloys for positive grid on efficiency of service characteristics (starting capacity, the electrolyte level changing under the charging and discharging) was investigated.

It is shown, that activation-ohmic items in empirical equations by Shepherd, Khaskina-Danilenko, Shepherd-Dasoyan, Romanov is abnormally describe of activation-ohmic processes at the discharge of accumulators a direct current. New expression U = RI + A ln(BI + 1) matching is offered to experimental data.

It has been shown that while in service of nickel-cadmium accumulators in their electrodes is collects a great amount of hydrogen.

Energy and power characteristics of supercapacitors with aqueous electrolyte and electrodes based on a carbonic material obtained of vegetal raw materials are investigated. Conditions for carbonization of the considered kinds of raw materials as well as a technology of the activation of the carbonized materials are established. It is shown that the activated materials prepared of corn smut and corn stigmas have high energy and power characteristics.

On base of voltammetric and chronovoltametric researches is carried out comparison of energy – power characteristics of electrodes made from single walls carbon nano- tubes (SWCNT) and from meso- porous carbon activated of FAS trade mark. High reversibility the charge processes for SWCNT it is discovered. The value of the interval of electrolyte decomposition potentials for SWCNT in sulfuric acid solutions exceeds 1.4 V. It is offered the power electrochemical superсapacitor, having specific power 20 kW/kg and specific energy 1 Wh/kg.