ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


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Kolomoets O. V., Maksyuta I. M., Chervakov O. V., Shembel' E. M. Lithium rechargeable work in the systems with polymer electrolytes based on C-PVC and PVDE. Electrochemical Energetics, 2008, vol. 8, iss. 1, pp. 51-57. DOI: 10.18500/1608-4039-2008-8-1-51-57, EDN: JVPANB

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article
EDN: 
JVPANB

Lithium rechargeable work in the systems with polymer electrolytes based on C-PVC and PVDE

Autors: 
Kolomoets O. V., Ukrainian State Chemical and Technological University
Maksyuta I. M., Ukrainian State Chemical and Technological University
Chervakov O. V., Ukrainian State Chemical and Technological University
Shembel' E. M., Enerize. Corp, Coral Springs, FL, USA
Abstract: 

Electrochemical behavior of Li in the systems with PE based on polymers of chlorinated polyvinylchloride and polyvinylidene fluoride were investigated by the method of cyclic voltammetry and galvanostatic cycling. Potentiodynamic investigations have shown that on lithium electrode even in the systems with polymer electrolyte the high current densities up to 5 mA/cm2 are realized. Influence of polymer electrolyte composition on the properties of the interface Li/electrolyte and rechargeable work of lithium electrode has been shown. The developed PE have been tested in the pilot prototypes of power sources of the system Li-LiMn2O4 и Li-MnO2.

Key words: 
Reference: 

1. Srinivasana V., Lippb L. // J. Electrochem. Soc. 2003. Vol. 150. P. K15.
2. Aurbach D., Zinigrad E., Teller H., Cohen Y., Salitra G., Yamin H., Dan P., Elster E. // J. Electrochem. Soc. 2002.Vol. 149. P. A1267.
3. Appetecchi G. B., Scaccia S., Passorini S. // J. Electrochem. Soc. 2000. Vol. 144. P. L136.
4. Pat. US2003031933 USA, МКИ H01B1/12; H01M10/40. Solid polymer electrolyte lithium battery.
5. Черваков O. В., Шембель E. M., Недужко Л. И., Глоба Н. И., Коломоец О. В., Новак П., Мешри Д. // Электрохимия. 2004. Т. 41, № 5. С. 578.
6. Webber A. // J. Electrochem. Soc. 1991.Vol. 138, № 9. Р. 2586.
7. Шембель Е. М., Максюта И. М., Ксенжек О. С. // Электрохимия. 1985. Т. 21.№ 8. С. 1016.

Received: 
28.02.2008
Accepted: 
28.02.2008
Published: 
31.03.2008