ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


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Synthesis and research of electrochemical properties of new gel electrolytes based on polyester diacrylates and 1 M LiBF4 in gamma-butirolactone

Gel polymer electrolytes (GPE) based on polyester diacrylates and 1 M LiBF4 in ? -butirolactone are synthesized and studied. Bulk conductivity has made (3.65 – 2.04)·10 – 3 Ohm –1·cm – 1 at room temperature for GPE with introduction 10 – 20 w/w. % polyester diacrylate. Temperature dependences of electrochemical properties of GPE in an interval from -17° up to +50°С are Studied. Electrochemical properties the GPE inserted in polypropylene separators of different kinds are investigated.

Lead-acid batteries for partial-state-of-charge applications

Effect of graphite addition to negative material and of new material of negative grids of VRLA batteries have been studied for partial-state-of-charge applications.

Chemical activation influence on the electrochemical and structural characteristics of the metal hydride electrode

A way of preliminary chemical activation of the MH electrode has been developed. A breadboard model of the battery with chemically activated MH electrodes was assembled and tested. The influence of preliminary chemical activation on the electrochemical and structural characteristics of the MH electrode was studied. The opportunity to exclude the technological operation of addition of metal binding materials into the active mass of the MH electrode is shown.

Effects of gaseous phase nucleation in kinetics of her on transition metals

Theoretical description of effect of gaseous phase 3D-nucleation in kinetics of cathodic hydrogen evolution reaction was made. Algorithm of separation of nucleation stream from general current of potentiostatic measurements was obtained. The system of critical coordinates for different nucleation models was created, their invariance to the nature of moving H or H2 particle on the electrode surface was shown.

Anmicroprocessor measuring complex for studying of noise characteristics of chemical power sources

Opportunities of creation of an accessible and rather inexpensive measuring complex for registration and researches of noise characteristics of various electrochemical objects, in particular chemical power sources, are considered. The device of the developed complex, its feature and key parameters are described. Comparison of operational characteristics of the device and the import equipment used for noise researches is brought.

Influence of tin on the behaviour of low-antimony lead alloys

The effects of tin additions in the range 0.5–3.0 wt.% on mechanical and electrochemical properties of Pb-Sb alloy are investigatead.

Influence of selenium on the behaviour of low-antimony lead alloys

The effects of selenium additions in the range 0.02–0.05 wt.% on mechanical and electrochemical properties of Pb-Sb alloy are investigatead.

Examination of Discharge Characteristics of AA Standard Size Nickel Metal Hydride Battery Cells at Negative Temperatures

Low-temperature test was held to determine the discharge characteristics of battery cells with the purpose to specify the requirements to electrode materials and electrolyte used in cylindrical nickel metal hydride battery cells of AA standard size that fit for work at negative temperatures.

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