porous structure

In this article was studied pressure influence in the electrode block of the model of the lead-acid accumulator on the most important physical properties (a specific surface, pore size distribution, compression properties, speed of capillary lifting of electrolyte) of absorbent glass mat separators of the trademarks «Hollingsworth» (USA) and "Bernard Dumas"(France) and on efficiency of an oxygen cycle. It is shown that the highest compression properties separators with a high specific surface (7-10 m2 /g) possess.

An analysis has been carried out of the capabilities of the known principles of gas utilization in hermetically sealed storage batteries (nickel-cadmium and lead-acidic ones) in comparison with the method based on gas absorbtion by the working (positive and negative) electrodes with forced gas feed. Special attention is paid to the control over gas-liquid flows in hermetically sealed vessels via the match between the porous structures of the separator matrices and the active masses of the working electrodes.

In this review electrochemical and structural data for the electrodes made of certain of perspective materials for supercapacitors are considered. These electrodes were made on the basis of high-dispersed carbon materials.

The most important structural and physicomechanical properties of absorbent glass mat separators «Hollingswoth and Vose», «Bernard Dumas», «BMSK AT Nippon» intended for lead-acid battery (LAB) are studied. It is shown that on pore size distribution strong influence puts the enclosed pressure: at compression 50 kPa there is a considerable reduction of the size of a pore.

The influence of porous structure of the absorptive glass mats manufactured by «Hollingsworth&Vose» (thickness 2.8 mm) and BernardDumas» (thickness 3.0 mm), modified by impregnation with polymeric emulsions on the basis of polyvinylidene fluoride (KYNAR), polyvinylpyrrolidone copolymer with styrene (PVS) and polytetrafluoroethylene (Tf), on the efficiency of ionization of hydrogen in lead-acid battery mock-ups.

Polymer membrane based on fluoropolymer F-42 was obtained by the method of electrospinning. The effect of the concentration of spinning solution and technological factors electrospinning process to its porous structure. It has been shown that increasing the spinning solution viscosity leads to an increase in pore size of the membrane obtained. Studied oxygen ionization process in the layout of the lead-acid battery separator with a two-layer based on glass fiber and polymer matrix membranes based on PTFE F-42.

The paper considers the most significant properties of moulding solutions based on a mixture of polyvinylidene fluoride and polystyrene for the process of capillary-free electrospinning nonwoven materials. It has been shown that the material obtained from the mixed solution of polyvinylidene fluoride and polystyrene in the ratio of components 0.75 : 0.25 is the largest porous, the diameter of the fibers is in the widest range from 0.14 to 2.8 ?m, and branching of the fibers is observed.

The efficiency of oxygen ionization in a lead-acid mock-up was studied using a separator based on an absorptive glass mat (AGM) and polymer non-woven fibrous materials based on F-2M polyvinylidene fluoride and polystyrene. Fibrous material obtained by capillary-free electrospinning. The technological and structural characteristics of the polymer material are investigated. It was found that the use of a sandwich polymer/AGM/polymer separator significantly increases the efficiency of oxygen ionization.

The effect of carbon materials of two types was studied: multi-walled carbon nanotubes (“Art-nano” of the NSU “S” brand (TU BU 690654933.001.-2011)) and multilayer graphene (“Art-nano GT” (TU BU 691460594.004–2017), and modifications by treatment with ozone and dimethylformamide (manufacturer LLC Advanced Research and Technology, Belarus) on the structural characteristics, capacity and utilization of the active mass of the negative electrode of a lead-acid battery.