ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Zhukovskii V. M., Bushkova O. V., Lirova B. I., Kruglyashov A. L. New lithium conducting polymer electrolytes for power sources. Electrochemical Energetics, 2001, vol. 1, iss. 1, pp. 43-49. DOI: 10.18500/1608-4039-2001-1-1-2-43-49, EDN: IVBLZF

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Full text:
download
(downloads: 297)
Language: 
Russian
Heading: 
Lithium and post‑lithium electrochemical systems
Article type: 
Article
UDC: 
541.122;541.8;541.133;546.34
DOI: 
10.18500/1608-4039-2001-1-1-2-43-49
EDN: 
IVBLZF

New lithium conducting polymer electrolytes for power sources

Autors: 
Zhukovskii V. M., The Ural State University of A. M. Gorky
Bushkova Ol'ga Viktorovna, Institute of Solid State Chemistry
Lirova B. I., The Ural State University of A. M. Gorky
Kruglyashov A. L., The Ural State University of A. M. Gorky
Abstract: 

The main roads of development in industrially useful solid polymer electrolytes (SPEs) are briefly reviewed. New SPEs based on acrylonitrile copolymers PBAN and PAN and lithium salts LiAsF6, LiCF3SO3, LiCIO4 have been obtained. The limits of salts solubility in polymer matrix PBAN were established. Ion solvation and ion association processes have been studied by IR spectroscopy. Conducting properties of SPEs were measured at 20-100°C. The existence of different ion transport mechanisms corresponding to different salt concentration regions are discussed.

Key words: 
solid polymer electrolytes
polyacrylonitrile
ion transport
Acknowledgments: 
The research described in this publication was made possible in part by Award No.REC-005 of the U.S. Civilian Research & Development Foundation for the Independent States of the Former Soviet Union (CRDF).
Reference: 
  1. Scrosati B., Neat R. // Applications of Electroactive Polymers / Ed. B.Scrosati. London: Chapman & Hall, 1993. P.182.
  2. Linford R.G. // Applications of Electroactive Polymers / Ed. B.Scrosati. London: Chapman & Hall, 1993. P.1.
  3. Bruce P.G., Gray F.М. // J. Solid State Electrochemistry. Cambrige: Cambridge University Press, 1995. P.119.
  4. Gray F.М. Solid Polymer Electrolytes: Fundamentals and Technological Applications. New York: VCH Publishers, Inc., 1991. 245 р.
  5. Berthier С. еt al. // Solid State lonics. 1983. V.11. Р.91.
  6. Orihara K., Yonekura H. // J. Macromol. Sci. 1990. V.27A. Р.1217.
  7. Florjanczyk Z., Wieczorek W. // Solid State Phenomena. 1994. Vol. 39-40. P. 161.
  8. Croce Е. et al. // J. Power Sources. 1990. Vol. 32. Р. 381.
  9. Capuano F., Croce F., Scrosati В. // J. Electrochem. Soc. 1991. V.138. P.1918.
  10. MacCallum J.R., Smith М.J., Vincent C.A. // Solid State Ionics. 1984. V.11. P.307.
  11. Cowie J.M.G. // Polymer Electrolyte Review-1 / Eds. J.R.MacCallum, C.A.Vincent. London: Elsevier, 1987. Р.92.
  12. Abraham K.M. // Applications of Electroactive Polymers / Ed. B.Scrosati. London: Chapman & Hall, 1993. P.96.
  13. Wright P.V. // Electrochim. Acta. 1998. V.43. Р.1137.
  14. Reihel I., Bayoudh S., Baudry Р., Majastre H. // Electrochim. Acta. 1998. V.43. P.1171.
  15. Chung S.H. et al. // Solid State lonics. 1998. V.112. P.153.
  16. Angell С.А., Liu C., Sanchez Е. // Nature (London). 1993. V.362. Р.137.
  17. McHattie G.S., Imrie C.T., Ingram M.D. // Electrochim. Acta. 1998. V.43. P.1151.
  18. Bruce P.G., Vincent C.A. // J. Faraday Discuss. Chem. Soc. 1989. V.88. P.43.
  19. Kruglyashov A.L. et al. // Solid State Phenomena. 1994. V.39-40. P.185.
  20. Animitsa I.E., Kruglyashov A.L., Bushkova O.V., Zhukovsky V.M. // Solid State lonics. 1998. V.106. P.321.
  21. Animitsa I.E., Volosentseva L.I., Zhukovsky V.M. // Solid State lonics. 1999. V.119. Р.245.
  22. Бушкова O.B., Лирова Б.И., Жуковский В.М. // Журн. Физ. химии. 1999. T.73. С.640.
  23. Ratner M. // Polymer Electrolyte Review-1 / Eds. J.R.MacCallum, C.A. Vincent. London: Elsevier, 1987. P.173.
  24. Boden N., Leng S.A., Ward I.M. // Solid State lonics. 1991. V.45. P.261.
  25. Bushkova O.V., Zhukovsky V.M., Lirova B.I., Kruglyashov A.L. // Solid State lonics. 1999. V.119. P.217.
  26. Плахотник В.Н., Товмаш H.Ф., Ковтун Ю.В. // Докл. АН СССР. 1987. Т.292. C.1426.
  27. MacCallum J.R., Vincent C.A. // Polymes Electrolyte Review-1 / Eds. J.R.MacCallum, C.A.Vincent. London: Elsevier, 1987. Р.23.
  28. Forsyth M. et al. // Solid State Ionics. 1992. V.53-56. P.1011.
Received: 
20.04.2000
Accepted: 
10.12.2000
Published: 
30.06.2001