ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Zhukovskii V. M., Bushkova O. V., Lirova B. I., Kruglyashov A. L. New lithium conducting polymer electrolytes for power sources. Electrochemical Energetics, 2001, vol. 1, iss. 1, pp. 43-?.

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article

New lithium conducting polymer electrolytes for power sources

Autors: 
Zhukovskii V. M., The Ural State University of A. M. Gorky
Bushkova Ol'ga Viktorovna, Institute of high-temperature Electrochemistry UB of RAS
Lirova B. I., The Ural State University of A. M. Gorky
Kruglyashov A. L., The Ural State University of A. M. Gorky
Abstract: 

The main roads of development in industrially useful solid polymer electrolytes (SPEs) are briefly reviewed. New SPEs based on acrylonitrile copolymers PBAN and PAN and lithium salts LiAsF6, LiCF3SO3, LiCIO4 have been obtained. The limits of salts solubility in polymer matrix PBAN were established. Ion solvation and ion association processes have been studied by 1R spectroscopy. Conducting properties of SPEs were measured at 20-100°C. The existence of different ion transport mechanisms corresponding to different salt concentration regions are discussed.