ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

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Burashnikova M. M., Panshin E. V. Influence of additives of carbon nanotubes and graphene to the active mass of the negative electrode of the lead-acid battery on its electrochemical characteristics. Electrochemical Energetics, 2023, vol. 23, iss. 2, pp. 95-106. DOI: 10.18500/1608-4039-2023-23-2-95-106, EDN: WHYSRI

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
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Language: 
Russian
Heading: 
Acid batteries
Article type: 
Article
UDC: 
541.136
DOI: 
10.18500/1608-4039-2023-23-2-95-106
EDN: 
WHYSRI

Influence of additives of carbon nanotubes and graphene to the active mass of the negative electrode of the lead-acid battery on its electrochemical characteristics

Autors: 
Burashnikova Marina Mikhailovna, Saratov State University
Panshin Egor Viktorovich, Saratov State University
Abstract: 

The electrochemical characteristics of the negative electrodes of the lead-acid battery with additives of carbon nanotubes and graphene were studied. It was shown that the highest values of the capacitive characteristics of the electrodes were obtained by adding carbon nanotubes to the negative active mass. The processes occurring on the negative electrode were studied by the method of impedance spectroscopy. Applying simulation, an equivalent electrical circuit was obtained, which adequately approximated the obtained frequency dependences. The elements of the proposed equivalent circuit were calculated. It was found that the injection of carbon additives increases the resistance R3 related to the porous structure of the electrodes.

Key words: 
lead-acid battery
negative active mass
carbon additive
discharge capacity
impedance
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Received: 
29.05.2023
Accepted: 
20.06.2023
Published: 
30.06.2023