ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

катодное внедрение

Prospective Composite Materials for Lithium~Ion Battery Cathodes Based on~Transition Metals Oxide and Rare Earth Elements Oxides Modified with Fullerene and Fluoride Ions

The review of cathode materials for lithium-ion batteries is presented, the analysis of advantages and application prospects of cathode materials on the basis of lithiated transition metals oxides is carried out. A method of heterovalent modification by ions of highly negative elements, lanthanum and its analogues for improving the electrochemical indices and stability of lithium manganese spinel is proposed. The effectiveness of fullerene, lithium fluoride, fullerenes halogen derivatives as modifying additive for MnO2 cathode materials has been noticed.

Cathodic Modification in Aqueous Phosphate­-Molibdate Solutions of Chitosan as a Way of Enhancing Hydride-Forming and Hydride-Accumulating Properties of Titanium

The electrochemical behavior of Ti electrode in aqueous solutions containing Na2MoO4 + H3PO4 + chitosan was investigated by methods of potential – time (E–t) curves at cathodic polarisation in galvanostatic mode, currentless chronopotentiometry, optic microscopy, X­ray spectral analysis of surface and determining roughness by measuring the wetting angle.

Analysis of the Influence of the Cathodic Polarization Value on the Amount of Hydrogen Sorption of Al-Sm with the Alloy of Electrochemical Measurements

The effect of cathodic polarization on the rate of hydrogen sorption from an aqueous organic electrolyte on an Al-Sm alloy using the potentiostatic and potentiodynamic methods were studied. The obtained data allowed us to calculate the diffusion-kinetic characteristics of this process, such as the interstitial constant, diffusion constant $C_{\text{Н}}\!\!\sqrt{D}$, constant current iconst, diffusion coefficient D and adsorption of hydrogen atoms G. The number of nuclei decreases, but their mass and radius increase in the potential range from –2.0 V to –2.4 V.

Elemental composition of the surface layers formed on titanium at the cathodic treatment in chitosan-containing aqueous-dimethyl sulfoxide solutions of phosphate-molybdate electrolyte

It was established that at the cathodic treatment of titanium in aqueous dimethyl sulfoxide solutions of sodium molybdate, containing phosphoric acid, at the potential of the cathodic incorporation of sodium (Ec  = ? 2.6 V) in the potentiostatic mode, the composition formed on the electrode surface layer depended not only on the composition of the solution, but also on the volume ratio of the aqueous electrolyte solution and the organic solvent (dimethyl sulfoxide).