ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Bushkova O. V., Lirova B. I., Zhukovskii V. M., Tyutyunnik A. P., Pivovarova N. V. Phase equilibria in the system poly(butadiene-CO-acrylonitrile) – lithium perchlorate. Electrochemical Energetics, 2002, vol. 2, iss. 3, pp. 116-?.

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article

Phase equilibria in the system poly(butadiene-CO-acrylonitrile) – lithium perchlorate

Autors: 
Bushkova Ol'ga Viktorovna, Institute of high-temperature Electrochemistry UB of RAS
Lirova B. I., The Ural State University of A. M. Gorky
Zhukovskii V. M., The Ural State University of A. M. Gorky
Tyutyunnik A. P., Institute of Chemistry of a Solid body UB of RAS
Pivovarova N. V., The Ural State University of A. M. Gorky
Abstract: 

Phase equilibria in the system poly(butadiene-co-acrylonitrile) (40:60) – LiClO4, had been studied by means of X-ray, optical microscopy and IR spectroscopy at 25-90°C. The results obtained demonstrate that the limit of the homogen ious area of the macromolecular ionic solution increase with temperature from 2.12 to 2.77 mol/dm. It was established that the temperature increase up to 90°C did not reveal the thermal destruction of the polymer matrix. The change of the individual poly(butadiene-co-acrylonitrile) (40:60) to the large scale produced butadiene-nitrile rubber with the same macromolecular backbone nature containing emulsifier (calcium stearate) and stabilizer (agidol-2) additives does not have remarkable influence on the phase equilibria in the system.