Polymer membrane based on fluoropolymer F-42 was obtained by the method of electrospinning. The effect of the concentration of spinning solution and technological factors electrospinning process to its porous structure. It has been shown that increasing the spinning solution viscosity leads to an increase in pore size of the membrane obtained. Studied oxygen ionization process in the layout of the lead-acid battery separator with a two-layer based on glass fiber and polymer matrix membranes based on PTFE F-42.