ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Galperin V. A., Kitsyuk E. P., Kulova T. L., Skundin A. M., Tuseeva E. K. Silicon electrodes degradation at cycling. Electrochemical Energetics, 2013, vol. 13, iss. 2, pp. 59-63. DOI: 10.18500/1608-4039-2013-13-2-59-63, EDN: RDNDCL

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Language: 
Russian
Article type: 
Article
EDN: 
RDNDCL

Silicon electrodes degradation at cycling

Autors: 
Galperin Valerii Aleksandrovich, Institute of Nanotechnologies of Microelectronics of RAS
Kitsyuk Evgenii Pavlovich, Technological Center Scientific-industrial Complex of MIET
Kulova Tat'yana L'vovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Skundin Aleksandr Mordukhaevich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Tuseeva Elena Konstantinovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Abstract: 

On basis of analysis of literature data as well as of own experimental results we suggest some regularity for degradation of silicon electrodes upon cycling. It was shown that an electrode capacity Q at n-th cycle can be calculated from equation Q = Q0 exp(kn+?n2/2), where Q0 is initial capacity value, k и ? are empiric constants.

Reference: 

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Received: 
22.05.2013
Accepted: 
22.06.2013
Published: 
22.06.2013