ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Kutlimuratov R. M., Kuznetsova A. R., Agafonov D. V., Surovikin Y. V. On the influence of the carbon material surface fraction determined by porosity on the linearity of the charge-discharge characteristics of DLSC. Electrochemical Energetics, 2023, vol. 23, iss. 4, pp. 207-216. DOI: 10.18500/1608-4039-2023-23-4-207-216, EDN: UVGNJG

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Full text:
(downloads: 41)
Language: 
Russian
Heading: 
Article type: 
Article
UDC: 
541.136
EDN: 
UVGNJG

On the influence of the carbon material surface fraction determined by porosity on the linearity of the charge-discharge characteristics of DLSC

Autors: 
Kutlimuratov Ruslanbek Muratbaevich, Saint Petersburg State Institute of Technology (Technical University)
Kuznetsova Arina Romanovna, Saint Petersburg State Institute of Technology (Technical University)
Agafonov Dmitrii Valentinovich, Saint Petersburg State Institute of Technology (Technical University)
Surovikin Yury Vital'evich, Center of New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences
Abstract: 

The electrical and chemical characteristics of nanocomposite materials based on carbon black for double-layer supercapacitors were investigated. It was shown that the highest values of the specific capacitive characteristics were obtained for carbon material SP4 which has the largest specific surface area (total capacity 228 F/g, reversible capacity 162 F/g). The results obtained in the work show the relevance of the problem under consideration and the necessity to continue the research to supplement the obtained experimental data for the pore distribution of materials in order to determine the influence of porosity on the physical and chemical characteristics.

Reference: 
  1. Conway В. Е. Electrochemical Supercapacitors. Scientific Fundamentals and Technological Applications. New York, Springer, 1999. 698 p. https://doi.org/10.1007/978-1-4757-3058-6
  2. Maltsev A. A. Surface modified, mesoporous and nanostructured carbon materials for electrochemical energy storage devices. Diss. Cand. Sci. (Chem.). Moscow, 2019. 134 p. (in Russian).
  3. Xiao Li, Wei Xing, Shuping Zhuo, Jin Zhou, Feng Li, Shi-Zhang Qiao, Gao-Qing Lu. Preparation of capacitor’s electrode from sunflower seed shell. Bioresource Technology, 2011, vol. 102, pp. 1118–1123. https://doi.org/10.1016/j.biortech.2010.08.110
  4. Yang K., Fan Q., Song C., Sun Y., Jiang W., Fu P. Enhanced functional properties of porous carbon materials as high-performance electrode materials for supercapacitors. Green Energy and Resources, 2023, vol. 1, pp. 3–4. https://doi.org/10.1016/j.gerr.2023.100030
  5. Youliang Cheng, Qingling Zhang, Changqing Fang, Jing Chen, Shaohua Guo, Xinchuan Che. Controllable morphologies and electrochemical properties of graphitizing MCMB-based hybrids with nanostructure via a simple chemical vapor deposition method. Journal of Alloys and Compounds, 2017, vol. 724, pp. 443–449. https://doi.org/10.1016/j.jallcom.2017.06.324
  6. Esarev I., Agafonov D., Surovikin Y., Nesov S., Lavrenov A. On the causes of non-linearity of galvanostatic charge curves of electrical double layer capacitors. Electrochimica Acta, 2021, vol. 390, article no. 138896. https://doi.org/10.1016/j.electacta.2021.138896
  7. Tekhnologicheskoe gorenie: kollektivnaya monografiya. Pod redaktsiei S. M. Aldoshina, M. I. Alymova [Aldoshin S. M., Alymova M. I., eds. Technological combustion: collective monograph]. Moscow, IPCP RAS, 2018. 611 p. (in Russian).
  8. Krause A., Kossyrev P., Oljaca M., Passerini S., Winter M., Balducci A. Electrochemical double layer capacitor and lithium-ion capacitor based on carbon black. J. Power Sources, 2011, vol. 196, pp. 8836–8842.
  9. Shaytanov A. G., Surovikin Yu. V., Syrieva A. V., Arbuzov A. B. Study of changes in the structure of carbon black particles after thermogas-chemical modification using vibrational spectroscopy. Dynamics of Systems, Mechanisms and Machines, 2018, vol. 6, no. 2, pp. 236–243 (in Russian). https://doi.org/10.25206/2310-9793-2018-6-2-236-243
Received: 
07.11.2023
Accepted: 
04.12.2023
Published: 
25.12.2023