ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

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Kulova T. L., Skundin A. M. Nafion-based solid polymer electrolytes for lithium-ion and sodium-ion batteries. Electrochemical Energetics, 2024, vol. 24, iss. 3, pp. 117-132. DOI: 10.18500/1608-4039-2024-24-3-117-132, EDN: HKYAMJ

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
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Language: 
Russian
Heading: 
Lithium electrochemical systems
Article type: 
Review
UDC: 
544.6:621.355
DOI: 
10.18500/1608-4039-2024-24-3-117-132
EDN: 
HKYAMJ

Nafion-based solid polymer electrolytes for lithium-ion and sodium-ion batteries

Autors: 
Kulova Tatiana L'vovna, A. N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS
Skundin Alexander Mordukhaevich, A. N. Frumkin Institute of Physical Chemistry and Electrochemistry RAS
Abstract: 

The use of solid polymer electrolytes is a novel and promising approach for enhancing the safety of lithium-ion and sodium-ion batteries. A number of publications on manufacturing electrolytes with lithium-ion and sodium-ion conductivity based on Nafion-like polymers have appeared in recent decade. The present mini-review analyses various methods of the synthesis of such electrolytes and their properties, as well as the information on laboratory lithium-ion and sodium-ion batteries using such electrolytes. The conclusion is made that the use of Nafion-based solid polymer electrolytes with Li+ and Na+ cation conductivity opens the way to creation of a new generation of lithium-ion and sodium-ion batteries. The principal advantage of Nafion-based solid polymer electrolytes over traditional PEO-based electrolytes is a fairly high cation transport number, which provides a sharp decrease in concentration polarization and, consequently, the increase in the energy efficiency of batteries.

Key words: 
solid polymer electrolytes
Nafion
cation conductivity
transport number
lithium-ion batteries
sodium-ion batteries
lithium-sulfur batteries
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Received: 
17.04.2024
Accepted: 
30.05.2024
Published: 
30.09.2024