ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Pantyukhina M. I., Plaksin S. V., Batalov N. N. Lithium-ionic conduction of solid solutions Li8Zr1 – xCexO6. Electrochemical Energetics, 2008, vol. 8, iss. 2, pp. 103-105. DOI: 10.18500/1608-4039-2008-8-2-103-105, EDN: JXGXWB

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Heading: 
Fuel cells
Article type: 
Article
DOI: 
10.18500/1608-4039-2008-8-2-103-105
EDN: 
JXGXWB

Lithium-ionic conduction of solid solutions Li8Zr1 – xCexO6

Autors: 
Pantyukhina M. I., Institute of high-temperature Electrochemistry UB of RAS
Plaksin S. V., Institute of high-temperature Electrochemistry UB of RAS
Batalov Nikolai Nikolaevich, Institute of high-temperature Electrochemistry UB of RAS
Abstract: 

In order to attain a higher conductivity of phase Li8ZrO6, which has the relatively higher conductivity and chemical stability to lithium the effect of substitution of Zr-sublattice was investigated. The homogeneous region of the solid solutions Li8Zr1 – xCexO6 was 0 ? x < 0.07. Transport properties of lithium ion conductors of the system Li8Zr1–xCexO6 were investigated (the electronic part of the total conductivity, concentration dependence of the total conductivity and the activation energy). It is establish that phase Li8ZrO6 and the solid solutions Li8Zr1–xCeXO6 mainly have a lithium-ionic conductivity.

Key words: 
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Reference: 

1. Пантюхина М. И., Андреев О. Л., Антонов Б. Д., Баталов Н. Н. // Журн. неорган. химии. 2002. Т. 47, № 11. С. 1778.
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5. Shannon R. D. // Acta Cryst. 1976. Vol. A32 Pt 5. P. 751–767.

Received: 
30.06.2008
Accepted: 
30.06.2008
Published: 
30.07.2008