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Apostolova R. D., Kolomoets O. V., Shembel' E. M. Electrolytic iron sulfides in the system of lithium power sourses with the electrolyte based on polyvinylchloride. Electrochemical Energetics, 2008, vol. 8, iss. 4, pp. 237-?. , EDN: KVLBAV

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Article type: 

Electrolytic iron sulfides in the system of lithium power sourses with the electrolyte based on polyvinylchloride

Apostolova R. D., Ukrainian State Chemical and Technological University
Kolomoets O. V., Ukrainian State Chemical and Technological University
Shembel' E. M., Enerize. Corp, Coral Springs, FL, USA

Discharge capacity of the synthesized by the authors electrolytic iron sulfides with the structure of Fe3S4, FeS in the models of lithium power sources with the gel electrolytes based on polyvinylchloride, lithium salts of LiClO4, LiCF3SO3 or LiN(CF3SO2)2 and propylene carbonate (PC) plasticizer is 240–300 mA·h.g–1 at cycling within the 2.8–1.1V range that is similar to the values reached in liquid-phase PC (LiClO4) electrolyte.

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1. Poizot P., Laruelle S., Grugeon S., Tarascon J.-M. // J. Electrochem. Soc. 2002. Vol. 149. P. 1212.
2. Yan J. M., Huang H. Z., Zhang J., Liu Z. J., Yang Y. // J. Power Sources. 2005. Vol. 146. P. 264.
3. Han S-C., Kim H-S., Song M-S., Lee P. S., Lee J-Y., Ahn H-J. // J. Alloys and Compounds. 2003. Vol. 349. P. 290.
4. Tomczuk Z., Tani B., Otto N. C., Roche M. F., Vissers D. R. // J. Electrochem. Soc. 1982. Vol. 129. P. 925.
5. Strauss E., Golodnitsky D., Peled E. // Electrochim Acta. 2000. Vol. 45. P. 1519.
6. Aпостолова Р. Д., Шембель Е. М. // Журн. прикл. химии. 1995. Т. 68. С. 1483.
7. Банник Н. Г., Недужко Л. И., Шембель Е. М. // Вопросы химии и химической технологии. 2005. № 3. С. 152.
8. Шембель Е., Апостолова Р., Нагирный В., Баскевич А., Литвин П. // Электрохимия. 2004. Т. 40. С. 821.
9. Шембель Е. М., Апостолова Р. Д., Тысячный В. П., Кирсанова И. В. // Электрохимия. 2005. Т. 41. С. 1465.
10. Apostolova R., Shembel E., Talyosef I., Grinblat J., Genish I., Markovsky B., Aurbach D. // Abstr. 8th Advanced Batteries and Accumulators. ABA-2007. Brno, 2007. P. 23.
11. Apostolova R., Maksjuta I., Shembel E., Markovsky B., Aurbach D. // Abstr. Russia-Japan Seminar on Advanced Materials and Processing. Novosibirsk, 2007. P. 97.
12. Tysyachny V. P., Shembel E. M., Apostolova R. D., Nagyrny V. M., Kylyvnyk K.Ye. // J. Solid State Electrochem. 2003. Vol. 8 P. 20.
13. Tysyachny V. P., Shembel E. M., Apostolova R. D., Nagirny V. M., Kylyvnyk K. E., Eskova N. I. // Solid State Ionics. 2004. Vol. 169. P. 135.
14. Shembel E. M., Chervakov O. V., Novak P., Neduzhko L. I., Reisner D. E., Meshri D., Polischuk Yu.V., Ribalka A. G. // Abstr. 6th Intern. Symposium Systems with Fast Ionic Transport. Cracow (Poland). 2001. P. IV-01.
15. Zhu W., Xie S. F., Zhang S. T., Huang Z. Q. // Fall Meeting. San Antonio, Texas, 1966. P. 101.
16. Alamagir M., Abraham K. M. // J. Power Sources. 1995. Vol. 54–1. P. 40.
17. Pistoia G., Antonini A., Wang G. // J. Power Sources. 1996. Vol. 58–2. P. 139.
18. Aurbach D., Talyosef Y., Markovsky B., Markevich E., Zinigrad E., Asraf L., Granaraj J. S., Kim H-J. // Electrochim. Acta. 2004.Vol. 50. P. 247.