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Кулова Т. Л., Скундин А. М. Проблемы оптимизации электрохимической системы безанодных натриевых аккумуляторов // Электрохимическая энергетика. 2026. Т. 26, вып. 1. С. 5-12. DOI: 10.18500/1608-4039-2026-26-1-5-12, EDN: NJWTJY

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Язык публикации: 
русский
Рубрика: 
Водородная энергетика
Тип статьи: 
Научная статья
УДК: 
544.6:621.355
DOI: 
10.18500/1608-4039-2026-26-1-5-12
EDN: 
NJWTJY

Проблемы оптимизации электрохимической системы безанодных натриевых аккумуляторов

Авторы: 
Кулова Татьяна Львовна, Институт физической химии и электрохимии им. А. Н. Фрумкина РАН
Скундин Александр Мордухаевич, Институт физической химии и электрохимии им. А. Н. Фрумкина РАН
Аннотация: 

При циклировании безанодных натриевых аккумуляторов возникает проблема несбалансированных объемных изменений разноименных электродов, что приводит к объемным изменениям аккумулятора в целом. При заряде отрицательного электрода увеличение объема составляет 0.88 см3 /А·ч. В настоящей работе оценено уменьшение объемов при заряде положительных электродов на основе ванадофосфата натрия, фторванадофосфата натрия, гексацианоферрата натрия и натрированного сульфида железа Na1.5FeS2. Сделан вывод, что при сопоставлении объемных изменений, а также удельной энергии и среднего разрядного напряжения аккумуляторов указанных электрохимических систем нельзя однозначно выбрать оптимальный вариант.

Ключевые слова: 
безанодный натриевый аккумулятор
объемные изменения
электрохимическая система
ванадофосфат натрия
фторванадофосфат натрия
гексацианоферрат натрия
натрированный сульфид железа
Благодарности: 
Работа поддержана грантом Российского научного фонда № 25-13-00125, https://rscf.ru/project/25-13-00125.
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Поступила в редакцию: 
01.12.2025
Принята к публикации: 
30.01.2026
Опубликована: 
31.03.2026