литий-ионный аккумулятор

Nanotubes of bronze titanium dioxide (TiO₂(B)) doped with vanadium were synthesized through hydrothermal reaction. The obtained material possesses mesoporous structure and large specific surface area of 180 m²/g. It was found that the incorporation of vanadium into TiO₂(B) lattice increases the volume of a unit cell. Additionally, the conductivity rose up to three orders of magnitude for doped titanium dioxide reaching the value of 1.70 ? 10 ^{? 8} S/cm.

Using literature information about the temperature effect on the electrochemical behavior of electrodes based on LiFePO₄ and Li₄Ti₅O₁₂ being positive and negative electrodes of a lithium­ion battery, the discharge characteristics of batteries with such electrodes and various ratios of the amount of active material on the electrodes in the temperature range from ?15 to +60°C were calculated.

The possibility of determining the charge state of lithium-sulfur batteries using the ANFIS model was estimated. Easily measurable in practice physical quantities were used as input parameters of the model. They are the battery voltage, the rate of its change and the number of previous cycles. The analysis of ANFIS models with various parameters (the number and type of membership functions) was carried out. It was shown that ANFIS is a model that makes it possible to estimate the charge state of a lithium-sulfur battery with the accuracy of more than 95%.