ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


борогидрид

The influence of impurities of the transition metals Fe, Ni, and Co on hydrolysis kinetics of BH?? ions in alkaline solutions

The influence of small amounts of the Fe, Co, and Ni impurities on the spontaneous hydrolytic process of borohydride was studied within a temperature range of 60–100°C. The object under study was a simulated solution containing 9.53 M of OH? ions and 0.14 M of BH4? ions, used as a fuel for borohydride fuel cells. The rate constant k of borohydride hydrolysis for a small amount of impurities at different temperature was estimated. The lowest non-accelerating concentrations of the impurities were established ( ? 10 ppm for iron? ?