ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Макаров А. А., Tret'yachenko E. V., Vikulova M. A., Bainyashev A. M., Rzaev V. А., Gorokhovsky A. V., Goffman V. G. Impedance spectroscopy of hollandite-like ceramic composite material of K2O-MnO-Cr2O3-TiO2 system. Electrochemical Energetics, 2025, vol. 25, iss. 1, pp. 33-44. DOI: 10.18500/1608-4039-2025-25-1-33-44, EDN: XCZYJY

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Full text:
download
(downloads: 11)
Language: 
Russian
Heading: 
Hydrogen energy
Article type: 
Article
UDC: 
546.56
DOI: 
10.18500/1608-4039-2025-25-1-33-44
EDN: 
XCZYJY

Impedance spectroscopy of hollandite-like ceramic composite material of K2O-MnO-Cr2O3-TiO2 system

Autors: 
Макаров Алексей Алексеевич, The Saratov State Technical University of Gagarin Yu. A.
Tret'yachenko Elena Vasil'evna, The Saratov State Technical University of Gagarin Yu. A.
Vikulova Mariya Aleksandrovna, The Saratov State Technical University of Gagarin Yu. A.
Bainyashev Aleksei Mikhailovich, The Saratov State Technical University of Gagarin Yu. A.
Rzaev Valerii А., The Saratov State Technical University of Gagarin Yu. A.
Gorokhovsky Alexander V., The Saratov State Technical University of Gagarin Yu. A.
Goffman Vladimir Georgievich, The Saratov State Technical University of Gagarin Yu. A.
Abstract: 

The electrochemical properties of a ceramic composite material in which a hollandite-like potassiumchromium titanate solid solution is presented as the main phase were studied using impedance spectroscopy. The dependences of the conductivity of the obtained composites on temperature in the range from 250 to 800°C were studied. The activation energies of volumetric, intergranular and grain volume conductivity were determined. The phase composition of the material and the crystallographic structures of individual phases were also established. 

Key words: 
potassium titanate
hollandite
conductivity
intergranular conductivity
phase composition
crystal lattice parameters
Reference: 
  1. Spearing S. M. Materials issues in microelectromechanical systems (MEMS). Acta Materialia, 2000, vol. 48, no. 1, pp. 179–196. https://doi.org/10.1016/S1359-6454(99)00294-3
  2. Hao S., Dongsheng Fu, Jialong Li, Songlin Mu, Yunjiao Li, Qingyan Shang. Preparation and dielectric properties of Ce-doped Ba(ZrxTi1–x)O3 ceramics. Research on Chemical Intermediates, 2015, vol. 41, pp. 3109–3116. https://doi.org/10.1007/s11164-013-1418-3
  3. Kit-Ying Chan, Baohua Jia, Han Lin, Nishar Hameed, Joong-Hee Lee, Kin-Tak Lau. A critical review on multifunctional composites as structural capacitors for energy storage. Composite Structures, 2018, vol. 188, pp. 126–142. https://doi.org/10.1016/j.compstruct.2017.12.072
  4. Gorokhovsky A. V., Tretyachenko E. V., Escalante-Garcia J. I., Yurkov G. Yu., Goffman V. G. Modified amorphous layered titanates as precursor materials to produce heterostructured nanopowders and ceramic nanocomposites. Journal of Alloys and Compounds, 2014, vol. 586, pp. S494–S497. https://doi.org/10.1016/j.jallcom.2012.10.054
  5. Tretyachenko E. V., Gorokhovsky A. V., Yurkov G. Y., Fedorov F. S., Vikulova M. A., Kovaleva D. S., Orozaliev E. E. Adsorption and photo-catalytic properties of layered lepidocrocite-like quasi-amorphous compounds based on modified potassium polytitanates. Particuology, 2014, vol. 17, pp. 22–28. https://doi.org/10.1016/j.partic.2013.12.002
  6. Gorokhovsky A., Saunina S., Maximova L., Tretyachenko E., Goffman V., Escalante-Garcia J. I., Vikulova M. Synthesis and electrical properties of the high-k ceramic composites based on potassium polytitanate modified by manganese. Research on Chemical Intermediates, 2022, vol. 48, no. 3, pp. 1227–1248. https://doi.org/10.1007/s11164-022-04669-x
  7. Gorokhovskii A. V., Tret’yachenko E. V., Kovaleva D. S., Vikulova M. A.. Synthesis and electrophysical properties of ceramic nanocomposites based on potassium polytitanate modified by chromium compounds. Glass and Ceramics, 2016, vol. 73, pp. 206–209. https://doi.org/10.1007/s10717-016-9857-0
  8. Makarov A. A., Tretyachenko E. V., Vikulova M. A., Saunina S. I. Study of the influence of sintering conditions of hollandite ceramics on its electrophysical properties. Khimicheskie problemy sovremennosti 2023: sbornik materialov VII Mezhdunarodnoi nauchnoi konferentsii studentov, aspirantov i molodykh uchenykh (Donetsk, 16–18 maya 2023 g.); otv. red. A. V. Belyi [Beliy A. V., ed. Chemical Problems of our Time 2023: Collection of Proc. from the VII International scientific conference of students, postgraduates and young scientists (Donetsk, May 16–18, 2023). Donetsk, Donetsk National University Publ., 2023, pp. 113–116. (in Russian).
  9. Gorokhovsky A. V., Escalante-Garc´ıa J. I., Sánchez-Monjarás T., Gutiérrez-Chavarr´ıa C. A. Synthesis of potassium polytitanate precursors by treatment of TiO2 with molten mixtures of KNO3 and KOH. Journal of the European Ceramic Society, 2004, no. 13, pp. 3541–3546. https://doi.org/10.1016/J.JEURCERAMSOC.2003.12.006
  10. Makarov A. A., Tretyachenko E. V., Vikulova M. A., Saunina S. I. Synthesis and properties of hollandites of the K2O-MNO-Cr2O3-TiO2 system based on potassium polytitanates. In: Perspektivnye materialy i vysokoeffektivnye protsessy obrabotki: sbornik materialov Vseros. molodezhnoy konf. (Saratov, 18–19 maya 2022 g.); pod. obshch. red. A. A. Fomina [Fomin A. A., total ed. Advanced Materials and Highly Efficient Processing Processes: Collection of Proc. of the All-Russian youth conf. (Saratov, May 18–19, 2022). Saratov, Saratov State Technical University Publ., 2022, pp. 140–142 (in Russian).
  11. Pouya Moetakef, Amber M. Larson, Brenna C. Hodges, Peter Zavalij, Karen J. Gaskell, Philip M. Piccoli, Efrain E. Rodriguez. Synthesis and crystal chemistry of microporous titanates Kx(Ti, M)8O16 where M = Sc–Ni. Journal of Solid State Chemistry, 2014, vol. 220, pp. 45– 53. https://doi.org/10.1016/j.jssc.2014.08.012
  12. Lucchesi S., Russo U., Della Giusta A. Crystal chemistry and cation distribution in some Mn-rich natural and synthetic spinels. European Journal of Mineralogy, 1997, vol. 9, no. 1, pp. 31–42. https://doi.org/10.1127/ejm/9/1/0031
  13. Khitrova V. I., Bundule M. F., Pinsker Z. G. Electron-diffraction study of titanium-dioxide in thin-films. Kristallography, 1977, vol. 22, no. 6, pp. 1253–1258. https://doi.org/10.1107/S0108767305086277
  14. Ruhemann F. Temperaturabhängigkeit der Gitterkonstanten von Manganoxyd. Physik. Ber., 1935, Bd. 16, S. 2337.
  15. Goffman V. G., Makarova A. D., Maksimova L. A., Gorokhovsky A. V., Tretyachenko E. V., Gorshkov N. V., Vikulova M. A., Baynyashev A. M. Tverdyy proton-provodyashchiy keramicheskiy elektrolit dlya nakopiteley energii (Solid proton-conducting ceramic electrolyte for energy storage devices). Electrochemical Energetics, 2021, vol. 21, no. 4, pp. 197–205 (in Russian). https://doi.org/10.18500/1608-4039-2021-21-4-197-205
  16. Ukshe E. A., Bukun N. G. Tverdyye elektrolity [Solid electrolytes]. Moscow, Nauka, 1977. 176 p. (in Russian).
  17. Lucía dos Santos-Gómez L., Javier Zamudio García, Jose Manuel Porras-Vazquez, Enrique R. Losilla, Marrero-López D. Nanostructured BaCo0.4Fe0.4Zr0.1Y0.1O3-δ cathodes with different microstructural architectures. Nanomaterials, 2020, vol. 10, no. 6, article no. 1055. https://doi.org/10.3390/nano10061055
  18. Grafov B. M., Ushke E. A. Elektrokhimicheskiye tsepi peremennogo toka: monografiya [Electrochemical circuits of alternating current: Monograph]. Moscow, Nauka, 1973. 128 p. (in Russian).
  19. Mark E. Orazem, Isabelle Frateur, Bernard Tribollet, Vincent Vivier, Sabrina Marcelin, Nadine Pébère, Annette L. Bunge, Erick A. White, Douglas P. Riemer, Marco Musiani. Dielectric properties of materials showing constant-phase-element (CPE) impedance response. Journal of The Electrochemical Society, 2013, vol. 160, no. 6, article no. C215. https://doi.org/10.1149/2.033306jes
  20. Shukdev Pandey, Devendra Kumar, Devendra Kumar, Lakshman Pandey, Equivalent circuit models using CPE for impedance spectroscopy of electronic ceramics. Integrated Ferroelectrics, 2017, vol. 183, no. 1, pp. 141–162. https://doi.org/10.1080/10584587.2017.1376984
  21. Ram M. Electrical analysis of a ceramic: LiCo3/5Mn1/5Cu1/5VO4. Physica B: Condensed Matter, 2010, vol. 405, no. 1, pp. 4201–4204. https://doi.org/10.1016/j.physb.2010.07.011 
Received: 
10.01.2025
Accepted: 
20.01.2025
Published: 
28.02.2025