Catalysts for oxygen reduction in the alkaline electrolyte based on multi-walled carbon nanotubes modified with urea and phthalocyanines of iron, cobalt and palladium were synthesized and studied. Physicochemical studies of the surface of the synthesized materials were carried out using porosimetry, Raman spectroscopy, X-ray phase analysis and X-ray photoelectron spectroscopy. The catalyst doped with metal phthalocyanines (MWCNT(Urea)_CoPc_FePc_Pd) has the largest surface area.