ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Kotsyubinskii V. O., Chelyadyn V. L., Il'nitskii R. V., Mironyuk I. F., Moklyak V. V., Kolkovskii P. I. The kinetic of lithium ions intercalation in the anatase synthesized by sol-gel methods. Electrochemical Energetics, 2011, vol. 11, iss. 4, pp. 179-183. DOI: 10.18500/1608-4039-2011-11-4-179-183, EDN: OWWFUB

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article
EDN: 
OWWFUB

The kinetic of lithium ions intercalation in the anatase synthesized by sol-gel methods

Autors: 
Kotsyubinskii V. O., Carpathian National University of V. Stefanik
Chelyadyn V. L., Carpathian National University of V. Stefanik
Il'nitskii R. V., Carpathian National University of V. Stefanik
Mironyuk I. F., Carpathian National University of V. Stefanik
Moklyak V. V., Institute of Metallophysics of G. V. Kurdyumov NAN of Ukraine
Kolkovskii P. I., Carpathian National University of V. Stefanik
Abstract: 

Possibility of ultradispersed TiO22 (anatase modification) using as the base of the lithium power sources cathode material obtained by chloride-acid hydrolysis of titanium tetrachloride has been studied. The researches of Li+ ions electrochemical intercalation kinetics and phasic model of the process was suggested. The cathode material phase composition changes during discharge were fixed and interpreted.

Reference: 

1. Bueno P. R., Leite E. R. // J. Phys. Chem. B. 2003. Vol. 107(34). P. 8868.
2. Schalkwijk W. A., Scrosati B. Advances in Lithium-Ion Batteries. New York: Kluwer Academic Plenum Publishers, 2002. 514 p.
3. Tremblay O., Dessaint L. A. // World Electric Vehicle J. 2009. Vol. 3. Р. 1.
4. Sayilkan F., Asilturk M., Sener S. // Turk J. Chem. 2007. № 31. P. 211.
5. Yongai Zhaia, Qing Zhanga, Fengqi Liua, Ge Gao // Materials Lett. 2008. Vol. 62(30). P. 4563.
6. Rath C., Mohanty P., Pandey A. C., Mishra N. C. // J. Phys. D: Appl. Phys. 2009. Vol. 42(20). Р. 205101.
7. Фатеев C. A., Рудаков В. М. // Электрохим. энергетика. 2005. Т. 5, № 4. С. 256.
8. Зобенкова В. А., Чуриков А. В. // Электрохим. энергетика. 2004. Т. 4, № 1. C. 29.
9. Wagemaker M., van de Krol R., Kentgens A., van Well A., Mulder F. // J. Amer. Chem. Soc. 2001. Vol. 123(46). Р. 11454.
10. Koudriachova M. V., de Leeuw S. W., Harrison N. M. // Physical Review B. 2004. Vol. 69(5). P. 054106.
11. Кулова Т. Л., Тарнопольский В. А., Скундин А. М. // Электрохимия. 2009. Т. 45, № 1. С. 42.
12. Dziewonski P., Grzeszczuk M. // J. Power Sources. 2009. Vol. 190. P. 545.
13. Liu S.-Q., Zhang J.-F., Huang K.-L., Yu J.-G. // J. Braz. Chem. Soc. 2008. Vol. 19(6). P. 1078.

Received: 
25.11.2011
Accepted: 
25.11.2011
Published: 
25.12.2011