ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Andreev O. L., Grigorov I. G., Batalov N. N. Synthesis of lithium metazirconate phase using thermodynamic simulations. Electrochemical Energetics, 2004, vol. 4, iss. 4, pp. 208-?.

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article

Synthesis of lithium metazirconate phase using thermodynamic simulations

Autors: 
Andreev O. L., Institute of high-temperature Electrochemistry UB of RAS
Grigorov I. G., Institute of Solid State Chemistry
Batalov Nikolai Nikolaevich, Institute of high-temperature Electrochemistry UB of RAS
Abstract: 

The optimal conditions for synthesis of lithium metazirconate phase with minimal contaminations has been determined using thermodynamic modeling method three routs were considers: solid state synthesis; sol-gel method and cocrystallization from nitrate solution. The results of calculations were proved by experiment. The sol-gel method was found to be most appropriate. The feasibility of control of product dispersion was shown.