ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Obukhov S. Г., Davydov D. Ю. Mathematical model of the electrochemical battery with physical constraints of available capacity. Electrochemical Energetics, 2023, vol. 23, iss. 3, pp. 121-133. DOI: 10.18500/1608-4039-2023-23-3-121-133, EDN: FYHKZY

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
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Language: 
Russian
Heading: 
Acid batteries
Article type: 
Article
UDC: 
621.355
DOI: 
10.18500/1608-4039-2023-23-3-121-133
EDN: 
FYHKZY

Mathematical model of the electrochemical battery with physical constraints of available capacity

Autors: 
Obukhov Sergey Геннадьевич, National Research Tomsk Polytechnical University
Davydov Denis Юрьевич, National Research Tomsk Polytechnical University
Abstract: 

The article presents a universal combined model of the electrochemical battery, built on the basis of the modified Shepherd equation and the kinetic model. The proposed model provides the adequate mapping of the basic characteristics of the battery in operating mode, taking into account the physical constraints of the capacity available. The results of verification of the developed mathematical model using lead-acid and lithium-iron-phosphate batteries are presented. These results prove its higher accuracy in comparison with the basic model of MATLAB/Simulink electrochemical battery.

Key words: 
energy storage unit
electrochemical battery
mathematical model
discharge characteristics
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Received: 
06.07.2023
Accepted: 
15.09.2023
Published: 
29.09.2023