ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

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Opra D. P., Gnedenkov S. V., Sinebryukhov S. L., Podgorbunskii A. B., Sokolov A. A., Ustinov A. Y., Kuryavyi V. G., Maiorov V. Y. Manganese-Doped Titanium Dioxide with Improved Electrochemical Performance for Lithium-Ion Batteries. Electrochemical Energetics, 2019, vol. 19, iss. 3, pp. 123-?. DOI: 10.18500/1608-4039-2019-19-3-123-140, EDN: DXWFAS

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Language: 
Russian
Heading: 
Lithium electrochemical systems
Article type: 
Article
DOI: 
10.18500/1608-4039-2019-19-3-123-140
EDN: 
DXWFAS

Manganese-Doped Titanium Dioxide with Improved Electrochemical Performance for Lithium-Ion Batteries

Autors: 
Opra Denis Pavlovich, Institute of Chemistry of Far-Easter Branch of RAS
Gnedenkov Sergei Vasil'evich, Institute of Chemistry of Far-Easter Branch of RAS
Sinebryukhov Sergei Leonidovich, Institute of Chemistry of Far-Easter Branch of RAS
Podgorbunskii Anatolii Borisovich, Institute of Chemistry of Far-Easter Branch of RAS
Sokolov Aleksandr Aleksandrovich, Institute of Chemistry of Far-Easter Branch of RAS
Ustinov Aleksandr Yur'evich, Institute of Chemistry of Far-Easter Branch of RAS
Kuryavyi Valerii Georgievich, Institute of Chemistry of Far-Easter Branch of RAS
Maiorov Vitalii Yur'evich, Institute of Chemistry of Far-Easter Branch of RAS
Abstract: 

Within the work, an influence of manganese dopant on electrochemical performance of anatase titanium dioxide (Mn/Ti = 0.05; 0.1; 0.2) had been investigated. It was established that incorporation of Mn3+ into the TiO2 lattice results in the formation of Ti1 ? xMnxO2 solid solution and increased anatase unit cell volume from 136.41 A3 (undoped sample) to 137.25 A3 (Mn/Ti = 0.05). The conductivity of doped TiO2 rises up to two orders in magnitude. Ti0.95Mn0.05O2 electrode delivers a capacity of 186 mA?h/g after 30 charge/discharge cycles at C/10, whereas the undoped TiO2 gives only 87 mA?h/g. At a high current rate of 2С the doped TiO2 (Mn/Ti = 0.05) maintains a reversible capacity of about 121 mA?h/g.

Key words: 
lithium-ion battery
anode
titanium dioxide
anatase
doping
cycleability
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Received: 
15.03.2019
Accepted: 
07.04.2019
Published: 
20.09.2019