ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Mikhailova A. A., Khazova O. A., Skundin A. M. Electrooxidation of Formic Acid at Nanostructural Composites of Palladium and Polyaniline. Electrochemical Energetics, 2018, vol. 18, iss. 3, pp. 128-132. DOI: 10.18500/1608-4039-2018-18-3-128-132, EDN: YSAXNJ

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
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Russian
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Article
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YSAXNJ

Electrooxidation of Formic Acid at Nanostructural Composites of Palladium and Polyaniline

Autors: 
Mikhailova Alla Aleksandrovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Khazova Ol'ga Alekseevna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Skundin Aleksandr Mordukhaevich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Abstract: 

DOI: https://doi.org/10.18500/1608-4039-2018-18-3-128-132

A kinetics of formic acid anodic oxidation at electrodes consisting from composites of palladium with polyaniline is studied. It was found that the contact of palladium with polyaniline does not result in the electrocatalytic activity enhancement, that differs such composites from composites of palladium with polyelectrolytes.

Reference: 

1. Yu X., Pickup P. G. Recent advances in direct formic acid fuel cells (DFAFC). J. Power Sources, 2008, vol. 182, pp. 124–132.

2. Rees N. V., Compton R. G. Sustainable energy: a review of formic acid electrochemical fuel cells. J. Solid-State Electrochem., 2011, vol. 15, pp. 2095–2100.

3. Jeon H., Jeong B., Joo J., Lee J. Electrocatalytic Oxidation of Formic Acid: Closing the Gap Between Fundamental Study and Technical Applications. Electrocatalysis. 2014, vol. 6, pp. 20–32.

4. Mikhailova A. A., Tuseeva E. K., Zhilov V. I., Khazova O. A., Skundin A. M. Electrooxidation of Formic Acid at Nanostructural Catalysts on the Base of Composites of Nanotubes, Polyelectrolytes, Platinum and Palladium. Elektrokhimicheskaya Energetika [Electrochemical Energetics], 2017, vol. 17, no. 1, pp. 29–36 (in Russian).

5. Maksimov Yu. M., Lapa A. S., Podlovchenko B. I. Adsorption of copper on palladium electrodes. Soviet Elecrochemistry, 1989, vol. 25, no. 5, pp. 634–637 (in Russian).

Received: 
25.05.2018
Accepted: 
25.05.2018
Published: 
21.08.2018