ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Popova M. A., Ushakov A. V. Electrode composites based on lithium-vanadium(III) phosphate and pyrolysis product of carbon black and starch. Electrochemical Energetics, 2026, vol. 26, iss. 2, pp. 91-97. DOI: 10.18500/1608-4039-2026-26-2-91-97, EDN: XHPVHA

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Full text:
(downloads: 4)
Language: 
Russian
Article type: 
Article
UDC: 
544.63
EDN: 
XHPVHA

Electrode composites based on lithium-vanadium(III) phosphate and pyrolysis product of carbon black and starch

Autors: 
Popova Mariya A., Saratov State University
Ushakov Arseni Vladimirovich, Saratov State University
Abstract: 

In this paper, we compare electrode composites based on Li3V2(PO4)3 and carbon according to their initial characteristics in the galvanostatic cycling mode and structural features. The composites were synthesized using carbon black or starch as carbon sources. The electrode material obtained using starch demonstrates a higher specific capacity, the stability of which is lower during cycling, while characterized by a smaller unit cell volume and a larger crystallite size.

Reference: 
  1. Kedrinsky I. A., Yakovlev V. G. Li-ionnyye akkumulyatory [Li-ion batteries]. Krasnoyarsk, Platina, 2002. 268 p. (in Russian).
  2. Choi D., Shamim N., Crawford A., Huang Q., Vartanian C. K., Viswanathan V. V., Paiss M. D., Alam M. J. E., Reed D. M., Sprenkle V. L. Li-ion battery technology for grid application. J. Power Sources, 2021, vol. 5, pp. 738–759. https://doi.org/10.1016/j.jpowsour.2021.230419
  3. Ushakov A. V., Makhov S. V., Gridina N. A., Ivanishchev A. V., Gamayunova I. M. Rechargeable lithium-ion system based on lithium-vanadium(III) phosphate and lithium titanate and the peculiarity of it functioning. Monatshefte für Chemie – Chemical Monthly, 2019, vol. 150, pp. 499–509. https://doi.org/10.1007/s00706-019-2374-4
  4. Makhov S. V., Ushakov A. V., Ivanishchev A. V., Gridina N. A., Churikov A. V., Gamayunova I. M., Volynskiy V. V., Klyuev V. V. Peculiarities of lithium pentatianate and lithium– vanadium(III) phosphate joint operation in the lithiumaccumulating system. Electrochemical Energetics, 2017, vol. 17, no. 2, pp. 99–119 (in Russian). https://doi.org/10.18500/1608-4039-2017-17-2-99-119
  5. Ivanishchev A. V., Ushakov A. V., Ivanishcheva I. A., Churikov A. V., Mironov A. V., Fedotov S. S., Khasanova N. R., Antipov E. V. Structural and electrochemical study of fast Li diffusion in Li3V2(PO4)3-based electrode material. Electrochimica Acta, 2017, vol. 230, pp. 479–491. https://doi.org/10.1016/j.electacta.2017.02.009
  6. Ivanishchev A. V., Churikov A. V., Ushakov A. V. Lithium transport processes in electrodes on the basis of Li3V2(PO4)3 by constant current chronopotentiometry, cyclic voltammetry and pulse chronoamperometry. Electrochimica Acta, 2014, vol. 122, pp. 187–196. https://doi.org/10.1016/j.electacta.2013.12.131
  7. Huang T., Guo X., Wang F., Zhang L., Zhou X., Xu Y., Wu C., Zeng W. Carbon coated Li3V2(PO4)3 derived from phytic acid with ultra-high rate performance for rechargeable Li ion batteries. Surfaces and Interfaces, 2024, vol. 52, art. 104900. https://doi.org/10.1016/j.surfin.2024.104900
  8. Ushakov A. V., Rybakov K. S., Khrykina A. V. Composite electrodes based on Li3V2(PO4)3, Li4Ti5O12 and carbon nanotubes: The influence of composition, thickness and surface morphology on electrochemical properties. Electrochemical Energetics, 2024, vol. 24, no. 3, pp. 133–149 (in Russian). https://doi.org/10.18500/1608-4039-2024-24-3-133-149
  9. Yin S.-C., Grondey X., Strobel P., Anne M., Nazar L. F. Electrochemical Property:  Structure Relationships in Monoclinic Li3-yV2(PO4)3. Journal of the American Chemical Society, 2003, vol. 125, no. 34, pp. 10402–10411. https://doi.org/10.1021/ja034565h
  10. Bagotskiy V. S., Skundin A. M. Khimicheskiye istochniki toka [Chemical power sources]. Moscow, Energoizdat, 1981. 360 p. (in Russian).
Received: 
07.05.2026
Accepted: 
21.05.2026
Published: 
30.06.2026