ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Popova S. S., Gots I. Y. Effect of the rare-earth element nature on the kinetics of electrochemical formation of Li-Mg-REE-Al alloys in the aluminum electrode-matrix. Electrochemical Energetics, 2003, vol. 3, iss. 2, pp. 91-?.

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article

Effect of the rare-earth element nature on the kinetics of electrochemical formation of Li-Mg-REE-Al alloys in the aluminum electrode-matrix

Autors: 
Popova Svetlana Stepanovna, Engelssky Institute of Technology of the Saratov State Technical University
Gots Irina Yur'evna, The Saratov State Technical University of Gagarin Yu. A.
Abstract: 

It was investigated kinetics of гаге earth metals (La, Pr, Sm, Lu) incorporation to aluminium and their influence on next magnesium and lithium incorporation from aprotic organic solutions of their salts to interval of temperature +50. ,.-20°C.
It was established, that the temperature of solution influences to velocity of incorporation process so to time of saturation of solid solution and to velocity of next process of electxocrystallization 1MC.
It was pointed, that electronic system of La3+ and Lu3+ ions, having highest stability, generated higher stability of phase β-LiAl in structure of Li-Mg-REE-Аl electrode.