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Vecherskii S. I., Konopel'ko M. A., Batalov N. N. Catalytic activity of LaLi0.1M0.1Fe0.8O3-d (M = Fe, Co, Ni) oxides for molten carbonate fuel cell. Part 1. Polarization Characteristics of Porous Gas Diffusion Electrodes in (Li0.62K0.38)2CO3 Melt. An Experimental Study. Electrochemical Energetics, 2014, vol. 14, iss. 3, pp. 133-140. DOI: 10.18500/1608-4039-2014-14-3-133-140, EDN: TQCJOT

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Catalytic activity of LaLi0.1M0.1Fe0.8O3-d (M = Fe, Co, Ni) oxides for molten carbonate fuel cell. Part 1. Polarization Characteristics of Porous Gas Diffusion Electrodes in (Li0.62K0.38)2CO3 Melt. An Experimental Study

Vecherskii Sergei Ivanovich, Institute of high-temperature Electrochemistry UB of RAS
Konopel'ko Maksim Alekseevich, Institute of high-temperature Electrochemistry UB of RAS
Batalov Nikolai Nikolaevich, Institute of high-temperature Electrochemistry UB of RAS

This paper presents polarization characteristics of porous gas diffusion cathodes prepared from LaLi0.1M0.1Fe0.8O3-d (M = Fe, Co, Ni) oxides with a perovskite related structure and Li0.1Ni0.9O oxide with a rock salt structure. The characteristics were measured in the laboratory scale fuel cell in the temperature range 820–1000 K. It has been shown that electrochemical activity of the cathodes with Co and Ni additives exceeds the activity of the Li0.1Ni0.9O cathode below 970 K.


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