The behavior of electrolytically deposited Pb and Zn in 40% perchloric acid at temperatures ranging from 30°C – +55°C. It is established that the electrochemical system Zn/HClO4/PbO2 has a higher discharge voltage and specific capacity compared to the system РЬ/НClO4/РЬO2. It is shown that in the temperature range from 0°C to +55°C the specific capacitance of the investigated electrochemical systems vary slightly.