ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Gavrillyuk A. A., Kuleshov V. N., Kurochkin S. V., Lanskaya I. I., Isaev Y. V. Ni-Mo and Ni-Mo-Co composite catalytic alloys for alkaline water electrolysis. Electrochemical Energetics, 2024, vol. 24, iss. 2, pp. 76-87. DOI: 10.18500/1608-4039-2024-24-2-76-87, EDN: TIOUZL

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
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Language: 
Russian
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Article type: 
Article
UDC: 
541.13
EDN: 
TIOUZL

Ni-Mo and Ni-Mo-Co composite catalytic alloys for alkaline water electrolysis

Autors: 
Gavrillyuk Andrew Alexandrovich, Moscow Power Engineering Institute
Kuleshov Vladimir Nikolaevich, Moscow Power Engineering Institute
Kurochkin Semyon V., Moscow Power Engineering Institute
Lanskaya Irina I., Moscow Power Engineering Institute
Isaev Yaroslav V., Moscow Power Engineering Institute
Abstract: 

Currently, a large number of studies on alkaline water electrolysis are being carried out with the aim of reducing the specific energy costs for the hydrogen evolution reaction and the oxygen evolution reaction. This work is devoted to the methods of synthesis of highly dispersed composite coating on the surface of nickel foam and the methods of the formation of bi- and ternary catalytic alloys based on molybdenum using electrochemical deposition. During the study of the samples morphological and element-by-element analyses were carried out and the activity indicators of the synthesized highly effective catalytic coatings were obtained.

Acknowledgments: 
The work was carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation within the framework of State Assignment No. FSWF-2023-0014 (Agreement No. 075-03-2023-383 dated January 18, 2023) in the field of scientific activity for 2023–2025.
Reference: 
  1. Pengcheng Zhao, Jingang Wang, Wei He, Liming Sun, Yun Li. Alkaline zero gap bipolar water electrolyzer for hydrogen production with independent fluid path. Energy Reports, 2022, vol. 9, no. 10, pp. 352–360. https://doi.org/10.1016/j.egyr.2023.05.135
  2. Korovin N. V., Kozlova N. I., Savel’veva O. N., Lapshina T. V. Moscow Order of Lenin Energy Institute. Method for manufacturing a porous electrode for electrochemical processes. Certificate of authorship no. 715646 SU, 1980 (in Russian).
  3. Sandhya Shetty, M. Mohamed Jaffer Sadiq, D. Krishna Bhat, A. Chitharanjan Hegde. Electrodeposition and characterization of Ni-Mo alloy as an electrocatalyst for alkaline water electrolysis. Journal of Electroanalytical Chemistry, 2017, vol. 796, pp. 57–65. https://doi.org/10.1016/j.jelechem.2017.05.002
  4. Chonglun Fan, D. L. Piron, P. Paradis. Hydrogen evolution on electrodeposited nickel-cobaltmolybdenum in alkaline water electrolysis. Electrochimica Acta, 1994, vol. 39, no. 18, pp. 2715–2722 https://doi.org/10.1016/0013-4686(94)00263-0
  5. Gao M. Y., Yang C., Zhang Q. B., Zeng J. R., Li X. T., Hua Y. X., Xu C. Y., Dong P. Facile electrochemical preparation of self-supported porous Ni-Mo alloy microsphere films as efficient bifunctional electrocatalyst for water splitting. Journal of Materlials Chemistry A, 2017, iss. 17, pp. 5797–5805. https://doi.org/10.1039/C6TA10812A
  6. Huan Liu, Daozhang Liu, Xu Cheng, Zhangsheng Hua, Shiwei He. One-step electrodeposition of Ni-Mo electrode with column-pyramid hierarchical structure for highly-efficient hydrogen evolution. Materials & Design, 2022, vol. 224, article no. 111427. https://doi.org/10.1016/j.matdes.2022.111427
  7. Qing Han, Shuang Cui, Nianwen Pu, Jianshe Chen, Kuiren Liu, Xujun Wei. A study on pulse plating amorphous Ni-Mo alloy coating used as HER cathde in alkaline medium. International Journal of Hydrogen Energy, 2010, vol. 35, iss. 11, pp. 5194–5201. https://doi.org/10.1016/j.ijhydene.2010.03.093
  8. Beltowska-Legman E., Indyka P. Kinetics of Ni-Mo electrodeposition from Ni-rich citrate baths. Thin Solid Films, 2012, vol. 520, iss. 6, pp. 2046–2051. https://doi.org/10.1016/j.tsf.2011.10.024
  9. Allam M., Benaicha M., Dakhouche A. Electrodeposition and characterization of NiMoW alloy as electrode material for hydrogen evolution in alkaline water electrolysis. International Journal of Hydrogen Energy, 2017, vol. 43, iss. 6, pp. 3394–3405. https://doi.org/10.1016/j.ijhydene.2017.08.012
  10. Jaksic M., Brun J., Johansen B., Tunold R. Some specific potentiodynamic features of nickel electrodes in alkaline aqueous media. International Journal of Hydrogen Energy, 1995, vol. 20, no. 4, pp. 265–273. https://doi.org/10.1016/0360-3199(94)E0019-U
  11. Mriappan V., Krishnamoorthy K., Pazhamalai P., Sahoo S., Kim S. Electrodepositied molybdenum selenide sheets on nickel foam as a binder-free electrode for supercapacitor application. Electrochimica Acta, 2018, vol. 265, pp. 514–522. https://doi.org/10.1016/j.electacta.2018.01.075
  12. Kuleshov V. N., Kurochkin S. V., Kuleshov N. V., Gavrilyuk A. A., Pushkareva I. V., Klimova M. A., Grigor’eva O. Yu. Alkaline Water Electrolysis with Anion-Exchange Membranes and NickelBased Catalysts. Electrochemistry, 2023, vol. 59, no. 11, pp. 915. https://doi.org/10.31857/S0424857023110105

 

Received: 
22.01.2024
Accepted: 
03.06.2024
Published: 
28.06.2024