For citation:
Ol'shanskaya L. N., Teryana E. M., Nichvolodin A. G. Thermodynamic characteristics of lithium intercalation in С8CrO3 electrode modified by addition of graphitizated soot. Electrochemical Energetics, 2001, vol. 1, iss. 4, pp. 49-?.
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Language:
Russian
Article type:
Article
Thermodynamic characteristics of lithium intercalation in С8CrO3 electrode modified by addition of graphitizated soot
Autors:
Ol'shanskaya Lyubov' Nikolaevna, The Saratov State Technical University of Gagarin Yu. A.
Teryana E. M., Engelssky Institute of Technology of the Saratov State Technical University
Nichvolodin Alexey Gennad'evich, JSC Elektroistochnik
Abstract:
By the method of equilibrium EMF (ЭДС) of system Li/Li+ solutiony/LixC8CrO3 in the interval of temperatures 283-333 К thermodynamic characteristics (TDC) (ΔG, ΔS, ΔH) of intercalation LixC8CrO3 were investigated. Changes of TDC in zone 0 < x < 1,0, x ≈ 1,1 and 1,3 < x < 1,6 are caused by the place of inculcated lithium ions on vacant places which differ by energy levels and are accompanied by regulating structure of forming combinations.
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