ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

суперионные проводники

Dimorphism of solid electrolytes with own structural disordering

The phenomenological model of transition ``low-conductive phase – electrolytic phase'' in crystals with own structural disordering is offered. The application of this model allowed to describe the behavior of thermodynamical characteristics of such crystals in the transition area and to propose an expression for the baric dependence of transition temperature. Analytical expressions for thermocinetical coefficients and for correlation between electric and thermal conductivity of solid electrolyte are obtained.