ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


растворимость

Phase diagrams of the ternary systems NaBH4–NaOH–H2O, KBH4–KOH–H2O, NaBO2–NaOH–H2O and KBO2–KOH–H2O by -10°С

A study of the solubility in the ternary systems NaBH4–NaOH–H2O, KBH4–KOH–H2O, NaOH–NaBO2–H2O и KOH–KBO2–H2O is of special fundamental and practical interest. The first two systems are used as a fuel and as a hydrogen source in hydrogen power engineering that includes the low-temperature fuel cells; borohydrides are converted into metaborates. Hence, the last two systems represent the discharged by-product.

Pressure influence on water electrolysis process with depolarization anode by sulfurous anhydride

Depolarization of anode by sulfurous anhydride allows to reduce power inputs on hydrogen production in 1.5 times. The reason which prevents commercialization of this process is realization impossibility of industrial electrolysis current density because of SO2 feeding diffusion limitation to anodic catalytic layer. Pressure influence on water electrolysis process with depolarization anode by sulfurous anhydride in solid polymer electrolyte electrolyzers is examined.