ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


отрицательный электрод

Peculiarities of sulfur electroreduction on the graphite electrode of lithium-ionic batteries

The additive into electrolyte SO2 allowing to realize the intercalation of lithium ions into spectral-pure graphite is shown in the work given. The monolayer of SO2 restoration products possessing the properties of solid inter phase electrolyte is formed on the material given. The formation of the surface layer requires 160±15 mA·h/g.

Modification of carbon materials for the lithium battery negative electrode with pyrolysis products of 3d metal-ethanolamine complexes

It was found that polynuclear complexes NiX2·2(fac-Co(Etm)3).], [NiX2·2[Co(Dctm)2] [NiX2·2[Co(HTetm)2], where Etm, Detm, Tetm are deprotonated molecules of mono- (NH2C2H4O) di- (NH(C2H4O)2) and tri-ethanolamine (N(C2H4O)3), after being inoculated onto the surface of graphite with subsequent pyrolysis in the inert atmosphere, become catalysts toward the reaction of Li intercalation into the graphite, thus imp

Materials of negative electrodes for rechargeable lithium batteries with aprotic organic electrolytes

Review of literature for 30 years on negative electrode materials (Li, Li, Me, Li, Cr) for rechargeable lithium batteries is presented. Problems of formation of surface passivating layers as well as electrodes activation techniques are considered. Interconnection and interdependence of kinetic characteristics and structural transformations in processes of lithium intercalation (extraction) to different materials are analyzed.