Cd|KOH|NiOOH

Zn|NH4CI|MnO2

Li|LiClO4|MnO2

Pb|H2SO4|PbO2

H2|KOH|O2

The dynamic character of processes taking place at aging of electrodes based on silicon composites

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).

УДК 544.65+621.355.9

DOI:  https://doi.org/10.18500/1608-4039-2016-16-1-3-9

The aging behaviour of thin-film multi-layered electrodes consisting from alternating layers of Si-O and Si-O-Al has been studied with using of electrochemical impedance spectroscopy (EIS). The equivalent circuit comprising weak inductance, ohmic resistance, and three parallel combinations of resistance and \text{CPE was proposed. The most interesting feature of the EIS data is non-monotonous change equivalent circuit components during the storage. This fact testifies dynamic character of SEI which manifests itself not only at the cycling but at OCP storage as well.

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