For citation:
Kachibaya E. I., Imnadze R. A., Paikidze T. V., Karseeva E. I., Korovin N. V., Kulova T. L., Skundin A. M. Structure and electrochemical properties of cobalt-doped lithium-manganese spinels for rechargeable lithium power sources. Electrochemical Energetics, 2002, vol. 2, iss. 1, pp. 12-?.
This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language:
Russian
Article type:
Article
Structure and electrochemical properties of cobalt-doped lithium-manganese spinels for rechargeable lithium power sources
Autors:
Kachibaya E. I., Institute of Inorganic Chemistry and Electrochemistry of R. I. Agladze of AN of Georgia
Imnadze R. A., Institute of Inorganic Chemistry and Electrochemistry of R. I. Agladze of AN of Georgia
Paikidze T. V., Institute of Inorganic Chemistry and Electrochemistry of R. I. Agladze of AN of Georgia
Karseeva E. I., Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Korovin Nikolai Vasil'evich, Moscow Power Engineering Institute
Kulova Tat'yana L'vovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Skundin Aleksandr Mordukhaevich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Abstract:
A series of doped lithium-manganese spinels with a common formula LiMn2-xСоxO4, 0 < х < 1, and LiMn2-x-yCrxСоyO4, 0 < х + у < 1, was synthesized. The structural and electrochemical properties of these compounds were studied. Replacement of Mn atoms in LiMn2O4 by Co or Co&Cr ones in a Mn:Me 195:5 ratio is shown to reduce the degradation of the discharge capacity at cycling with no decrease of its magnitude.
Journal issue: