ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

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Shablovskii Y. O. Spectral Analysis of Nonharmonic and Polyharmonic Responses of an Electrochemical Object at Impedance Measurements. Electrochemical Energetics, 2012, vol. 12, iss. 3, pp. 111-116. DOI: 10.18500/1608-4039-2012-12-3-111-116, EDN: PLGYPX

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Spectral Analysis of Nonharmonic and Polyharmonic Responses of an Electrochemical Object at Impedance Measurements

Shablovskii Yaroslav Olegovich, The Gomel State Technical University of P. O. Dry

Possibilities for increasing efficiency of impedance spectral measurements are investigated. It is shown that for determination of linear electrochemical impedance a linearly changing input signal is preferable, and for the quantitative estimation of non-linearity of electrochemical impedance as an input signal it is expedient to use the cosine electric beats. The constructive diagrams of generators of such signals are offered.


1. Ivers-Tiffee Е., Weber A., Schichlein Н. Electrochemical impedance spectroscopy. Handbook of Fuel Cells. Fundamentals, Technology and Applications / eds. by W. Vielstich, H. A. Gasteiger, A. Lamm. West Sussex: John Wiley & Sons Ltd, 2003. P. 220–235.
2. Barsoukov E., Macdonald J. R. Impedance Spectroscopy: Theory, Experiment, and Applications. 2nd ed. John Wiley & Sons, 2005. 608 p.
3. Коровин H. В. Электрохимическая энергетика. M.: Энергоатомиздат, 1991. 264 с.
4. Linden's Handbook of Batteries. 4th ed. New York: McGraw-Hill, 2010. 1200 p.
5. Gabrielli C. Identification of Electrochemical Processes by Frequency Response Analysis. // Solartron ANALYTICAL/Technical Report # 004/83, iss. 3, Match. 1998.
6. Буянова E. С., Емельянова Ю. В. Учебно-методический комплекс дисциплины «Импедансная спектроскопия электролитических материалов». / Урал. гос. ун-т. Екатеринбург, 2008. URL: http // (дата обращения: 01.08.2012).
7. Chang B.-Y, Park S.-M. Electrochemical Impedance Spectroscopy // Annual Review of Analytical Chemistry. 2010. Vol. 3. P. 207–229.
8. Park S.-М., Yoo J.-S. Electrochemical Impedance Spectroscopy // Analytical Chemistry. 2003. Vol. 75. P. A455-A461.
9. Barsoukov E., Ryu S., Lee H. A novel impedance spectrometer based on carrier function Laplace-transform of the response to arbitrary excitation // J. Electro anal. Chem. 2002. Vol. 536, № 1–2. P. 109–122.
10. Yoo J.-S., Park S.-M. // An Electrochemical Impedance Measurement Technique Employing Fourier Transform // Anal. Chem. 2000. Vol. 72, № 9. P. 2035–2041.
11. Стойнов 3. Б., Графов Б. M., Савова-Стойнова Б. С., Елкин В. В. Электрохимический импеданс. М.: Наука, 1991. 336 с.
12. Зевеке Г. В., Ионкин П. А., Нетушил А. В., Страхов С. В. Основы теории цепей. 5-е изд. М.: Энергоатомиздат, 1989. 528 с.
13. Ifeachor Е. С., Jervis В. W. Digital Signal Processing. 2nd ed. Prentice Hall, 2002. 933 p.
14. Orazem M., Tribollet B. Electrochemical Impedance Spectroscopy. John Wiley & Sons, 2008. 560 p.
15. Афанасьев А. В., Москвичев A. H., Москвичев A. A. Низкочастотный комплекс импедансных измерений характеристик проводящих сред // Вести. Нижегород. ун-та. Радиофизика. 2008. № 3. С. 60–64.