Cd|KOH|NiOOH

Zn|NH4CI|MnO2

Li|LiClO4|MnO2

Pb|H2SO4|PbO2

H2|KOH|O2

Solid oxide fuel cells with film electrolyte: problems and perspectives

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).

УДК 539.23 + 544.6.018

DOI:  https://doi.org/10.18500/1608-4039-2016-16-4-196-206

This paper reviews the methods used nowadays for solid-oxide electrolyte film deposition. Problems and perspectives in the field of development of solid oxide fuel cells with film electrolyte are discussed.

Literature
  1. Kariya T., Uchiyama K., Tanaka H., Hirono T., Kuse T., Yanagimoto K., Henmi M., Hirose M., Kimura I., Suu K., Funakubo H. Intermediate-temperature operation of solid oxide fuel cells (IT-SOFCs) with thin film proton conductive electrolyte. J. Physics : Conference Series, 2015, vol. 660, pp. 012057. DOI: 10.1088/1742-6596/660/1/ 012057.
  2. Ko C., Kerman K., Ramanathan S. Ultra-thin film solid oxide fuel cells utilizing un-doped nanostructured zirconia Electrolytes. J. Power Sources, 2012, vol. 213, pp. 343–349. DOI: 10.1016/j.jpowsour.2012.04.034.
  3. Soloviev A. A., Sochugov N. S., Shipilova A. V., Efimova K. B., Tumashevskaya A. E. Mid-Temperature Solid Oxide Fuel Cells with Thin Film ZrO2 : Y2O3 Electrolyte. Russian J. Electrochemistry, 2011, vol. 47, no. 4, pp. 494–500.
  4. Sochugov N. S., Soloviev A. A., Shipilova A. V., Rotshtein V. P. An ion-plasma technique for formation of anode-supported thin electrolyte films for IT-SOFC applications. Intern. J. Hydrogen Energy, 2011, vol. 36, pp. 5550–5556. DOI: 10.1016/j.ijhydene.2011.01.159.
  5. Solovyev A. A., Shipilova A. V., Ionov I. V., Kovalchuk A. N., Rabotkin S. V., Oskirko V. O. Mag- netron-Sputtered YSZ and CGO Electrolytes for SOF C. J. Electronic Materials, 2016, vol. 45, pp. 3921–3928. DOI: 10.1007/s11664–016–4462-0.
  6. Putkonen M., Sajavaara T., Niinisto J., Johansson L.-S., Niinisto L. Deposition of yttria-stabilized zirconia thin films by atomic layer epitaxy from β-diketonate and organometallic precursors. J. Mater. Chem., 2002, vol. 12, pp. 442–448. DOI: 10.1039/B107799F.
  7. Shim J. H., Chao C., Huang H., Prinz F. B. Atomic Layer Deposition of Yttria stabilized Zirconia for Solid Oxide Fuel Cells. Chem. Mater., 2007, vol. 19, pp. 3850–3854. DOI: 10.1021/cm070913t.
  8. Su P. C., Chao C. C., Shim J. H., Fasching R., Prinz F. B. Solid Oxide Fuel Cell with Corrugated Thin Film Electrolyte. Nano Lett., 2008, vol. 8, pp. 2289–2292. DOI: 10.1021/nl800977z.
  9. Elam J. W., Dasgupta N. P., Prinz F. B. ALD for clean energy conversion, utilization, and storage. MRS Bulletin, 2011, vol. 36, pp. 899–906. DOI: 10.1557/mrs.2011.265.
  10. Ha S., Su P.-C., Cha S.-W. Combinatorial deposition of a dense nano-thin film YSZ electrolyte for low temperature solid oxide fuel cells. J. Mater. Chem. A, 2013, vol. 1, pp. 9645–9649. DOI: 10.1039/C3TA11758H.
  11. Gelfond N. V., Morozova N. B., Igumenova I. K. Application of Zr(IV) and Y(III) beta-diketonate derivatives in MOCVD of YSZ film electrolyte for SOF C. Advances in Coordination, Bioinorganic and Inorganic Chemistry, Bratislava, Slovak Technical University Press, 2005, pp. 156–159.
  12. Predtechenskii M. R., Bobrenok O. F., Gelfond N. V. TOTE s tonkoplenochnym elektrolitom [SOFC with thin-film electrolyte]. Tezisy XIII Rossiiskoi konferentsii po fizicheskoi khimii i elektrokhimii rasplavlennyh i tverdyh elektrolitov [Abstracts of XIII Russian conference on physical chemistry and electrochemistry of molten and solid electrolytes]. Ekaterinburg, 2004, pp. 54 (in Russian).
  13. Gelfond N. V., Bobrenok O. F., Predtechensky M. R., Morozova N. B., Zherikova K. V., Igumen- ov I. K. Chemical Vapor Deposition of Electrolyte Thin Films Based on Yttria-Stabilized Zirconia. Inorganic Materials, 2009, vol. 45, pp. 659–665.
  14. Beresnev S. M., Bobrenok O. F., Kuzin B. L., Bogdanovich N. M., Kurteeva A. A., Osinkin D. A., Vdovin G. K., Bronin D. I. Single Fuel Cell with Supported LSM Cathode. Rus. J. Electrochemistry, 2012, vol. 48, no. 10, pp. 969–975.
  15. Kuzmin A. V., Stroeva A. Yu., Gorelov V. P. Protonprovodyaschie oksidy na osnove LaScO3 v tonko- plenochnom i keramicheskom sostoyanii [Proton conducting oxides based on LaScO3 in thin-film and ceramic states]. Fiziko-khimicheskie problemy vozobnovlyaemoi energetiki. Trudy Rossiiskoi konferentsii [Proc. Russ. Conf. «Physical and chemical problems of renewable energetics»]. Sankt Petersburg, 2013, pp. 31–32 (in Russian).
  16. Dunyushkina L. A., Smirnov S. V., Plaksin S. V., Kuimov V. M., Gorelov V. P. The Across-Plane Conductivity and Microstructure of SrZr0.95Y0.05O3−δ Thin Films. Ionics, 2013, vol. 19, pp. 1715–1722. DOI: 10.1007/s11581–013–0910-5.
  17. Dunyushkina L. A., Smirnov S. V., Kuimov V. M., Gorelov V. P. Electrical Conductivity of CaZr0.9Y0.1O3−δ Films Deposited from Liquid Solutions. Intern. J. of Hydrogen Energy, 2014, vol. 39, pp. 18385–18391. DOI: 10.1016/j.ijhydene.2014.09.008
  18. Dunyushkina L. A. Vvedenie v metody polucheniya plenochnyh elektrolitov dlya tverdooksidnyh toplivnyh elementov [Introduction in methods of preparation of film electrolytes for solid oxide fuel cells]. Ekaterinburg, Publishig polygraphic center, 2015. 126 p.
  19. Dunyushkina L. A., Pankratov A. A., Gorelov V. P., Brouzgou A., Tsiakaras P. Deposition and Charac- terization of Y-doped CaZrO3 Electrolyte Film on a Porous SrTi0.8Fe0.2O3−δ Substrate. Electrochimica Acta, 2016, vol. 202, pp. 39–46. DOI: 10.1016/j.electacta.2016.03.120
  20. Dunyushkina L. A., Kuimov V. M., Pankratov A. A., Reznitskih O. G., Khaliullina A. S. Synthesis, Microstructure, and Electric Properties of CaZr0.9Y0.1O3−δ Films Obtained on Porous SrTi0.8Fe0.2O3−δ Substrates. Rus. J. Electrochemistry, 2016, vol. 52, no. 11, pp. 1057–1063.
  21. Ishihara T., Sato K., Takita Y. Electrophoretic Deposition of Y2O3-Stabilized ZrO2 Electrolуte Films in Solid Oxide Fuel Cells. J. Am. Ceram. Soc., 1996, vol. 79, no. 4, pp. 913–919. DOI: 10.1111/j.1151-2916.1996.tb08525.x.
  22. Sarkar P., Huang X., Nicholson P. S. Zirconia-Alumina Functionally-Gradiented Composites by Elec- trophoretic Deposition Techniques. J. Am. Ceram. Soc., 1993, vol. 76, no. 4, pp. 1055–1056DOI-: 10.1111/j.1151- 2916.1993.tb05335.x.
  23. Meepho M., Wattanasiriwech D., Wattanasiriwech S., Aungkavattana P. Preparation of NiO-YSZ Substrate for Electrophoretic Deposition of thin YSZ Film. Energy Procedia, 2013, vol. 34, pp. 714–720. DOI: 10.1016/ j.egypro.2013.06.804.
  24. Safronov A. P., Kalinina E. G., Kotov Yu. A., Murzakaev A. M., Timoshenkova O. R. Elektroforeticheskoe osazhdenie nanoporoshkov na poristoi poverhnosti [Electrophoretic deposition of nanopowders on porous surface]. Rossiiskie nanotekhnologii [Rus. nanotechnologies], 2006, vol. 1, no. 1–2, pp. 162–169 (in Russian).
  25. Kalinina E. G. Fiziko-khimicheskie zakonomernosti elektroforeticheskogo osazhdeniya tonkoplenochnogo tverdogo elektrolita na osnove ZrO2. Diss. Kand. khim. nauk. [Physical and chemical regularities of electrophoretic deposition of thin-film solid electrolyte based on ZrO2. Dr. chem. sci. diss.]. Ekaterinburg, 2010. 152 p.
  26. Zou Y., Zhou W., Sunarso J., Liang F., Shao Z. Electrophoretic deposition of YSZ thin-film electrolyte for SOFCs utilizing electrostatic-steric stabilized suspensions obtained via high energy ball milling. Intern. J. Hydrogen Energy, 2011, vol. 36, pp. 9195–9204. DOI: 10.1016/j.ijhydene.2011.04.187.
  27. Courtin E., Boy P., Piquero T., Vulliet J., Poirot N., Laberty-Robert C. A composite sol-gel process to prepare a YSZ electrolyte for Solid Oxide Fuel Cells. J. Power Sources, 2012, vol. 206, pp. 77–83. DOI: 10.1016/ j.jpowsour.2012.01.109
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