ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Eliseeva S. N., Levin O. V., Tolstopyatova E. G., Alekseeva E. V., Apraksin R. V., Rumyantsev A. M., Zhdanov V. V., Kondrat'ev V. V. Properties of LiFePO4-based cathode material with additions of conducting polymer for Li–ion batteries. Electrochemical Energetics, 2015, vol. 15, iss. 1, pp. 39-44. DOI: 10.18500/1608-4039-2015-15-1-39-44, EDN: UDFJHP

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article
EDN: 
UDFJHP

Properties of LiFePO4-based cathode material with additions of conducting polymer for Li–ion batteries

Autors: 
Eliseeva Svetlana Nikolaevna, Institute of Chemistry, St.-Petersburg State University
Levin Oleg Vladislavovich, Institute of Chemistry, St.-Petersburg State University
Tolstopyatova Elena Gennad'evna, Institute of Chemistry, St.-Petersburg State University
Alekseeva Elena Valer'evna, Institute of Chemistry, St.-Petersburg State University
Apraksin Rostislav Valer'evich, Institute of Chemistry, St.-Petersburg State University
Rumyantsev A. M., JSC Accumulator Company Rigel
Zhdanov V. V., JSC Accumulator Company Rigel
Kondrat'ev Veniamin Vladimirovich, Institute of Chemistry, St.-Petersburg State University
Abstract: 

In this study, the electrochemical behavior and properties of the novel LiFePO4-based composite cathode material with a water-soluble binder LA-133 and a conductive polymer PEDOT:PSS (poly-3,4-ethylenedioxythiophene: polystyrenesulfonate) as an aqueous dispersion were studied. Using the conductive polymer in combination with a water-soluble binder LA-133 allows to reduce the proportion of electrochemically inactive components (up to 10\%) and thus to increase its specific capacity for a given weight of the active material. The capacity values for the most promising cathode material obtained were 146 mA h/g (at 0.2C) and 141 mA h/g (at 1C).
Key words: lithium iron phosphate, poly-3,4-ehthylenedioxythiophene, Li-ion batteries, charge-discharge curves.

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Received: 
15.01.2015
Accepted: 
15.01.2015
Published: 
25.02.2015