ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)

For citation:

Pleshakov M. S., Yalyushev N. I., Fedotov D. B., Rybalov A. M. On the reasons of decrease in capacity of stored lithium-thionylchloride chemical power sourced. Electrochemical Energetics, 2004, vol. 4, iss. 4, pp. 227-?.

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Language: 
Russian
Article type: 
Article

On the reasons of decrease in capacity of stored lithium-thionylchloride chemical power sourced

Autors: 
Pleshakov M. S., Scientific Design-technology Bureau of Chemical Sources of Current (SDTBCSC)
Yalyushev Nikolai Ismailovich, The Southern Russian State Polytechnical University (NPI) of M. I. Platov
Fedotov Dmitrii Borisovich, JSC IF Orion-HIT
Rybalov A. M., The Southern Russian State Polytechnical University (NPI) of M. I. Platov
Abstract: 

The reasons of decrease in capacity of fithium-thionyl chloride elements after long storage are considered. It is shown the discharge voltage reduction after storage is caused not only by passivation of a lithium electrode but also by passivation of a carbon electrode. The assumption is proved that passivation of the carbon electrode is caused by formation of a layer of reactions products, which proceed in local galvanic pairs «a collector of a current – an electrode material».