ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


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Dribinskii A. V., Lukovtsev V. P., Lukovtseva N. V., Semenova V. A. Investigation of the Initial Stages of Anode Dissolution at High-frequencies in Lithium tionyl Chloride Cells. Electrochemical Energetics, 2018, vol. 18, iss. 3, pp. 122-127. DOI: 10.18500/1608-4039-2018-18-3-122-127, EDN: YSAXNB

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Russian
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Article
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YSAXNB

Investigation of the Initial Stages of Anode Dissolution at High-frequencies in Lithium tionyl Chloride Cells

Autors: 
Dribinskii Aleksandr Veniaminovich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Lukovtsev Vyacheslav Pavlovich, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Lukovtseva Nina Vladimirovna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Semenova Valentina Anatol'evna, Institute of Physical Chemistry and Electrochemistry of A. N. Frumkina of RAS
Abstract: 

DOI: https://doi.org/10.18500/1608-4039-2018-18-3-122-127

Impedance spectroscopy was used to study the initial stages of lithium anode dissolution in SAFT LS-33600 cells at frequencies more than 35 Hz. It was found that experimental results can be described by the dissolution of metals covered by a passive film, including the stages of film dilatation and breakdown of the film.

Reference: 

1. Minichandraiah N. Electrochemical impedance studies of a decade-aged magnesium / manganese dioxide primary cell. J. Appl. Electrochem., 1999, vol. 10, рр. 463–471.

2. Saft Batteries. Available at : http://https://www.saftbatteries.com/products-solutions/products/ls-lsh?page=1 (accessed 10 March 2018).

3. Petrenko E. M., Dribinskii A. V., Lukovtsev V. P., Klyuev A. L. Otsenka sostoyaniya litievykh khimicheskikh istochnikov toka metodom impedansnoi spektroskopii [Evaluation of the state of lithium chemical sources of current using the method of impedance spectroscopy]. Elektrokhimicheskaya energetika [Electrochemical Energetics], 2010, vol. 10, no. 3, рр. 128–132 (in Russian).

4. Dey A. N. S.E.N. studies of the Li-film growth and the voltage- delay phenome nor associated with the litium-thionyl chloride inorganic electrolyte system. Electrochim. Acta, 1976, vol. 21, №. 5, рр. 377–382.

5. Dribinskii A. V., Lukovtsev V. P., Petrenko E. M. Elektrokhimicheskii impedans litii-tionilkhloridnykh istochnikov toka v vysokochastotnoi oblasti spectra [Electrochemical impedance of lithium-thionyl chloride current sources in the high-frequency range]. Aktual’nye problemy gumanitarnykh i estestvennykh nauk [Actual Problems of the Humanities and Natural Sciences], 2015, vol. 82, no. 11, pp. 17–18 (in Russian).

6. Ratna Kumar B. V., Sathyanaroyand S. The delayed action of magnesium anodes in primary batteries. Part I. Experimental studies. J. Power Sources, 1983, vol. 10, рр. 219–241.

Received: 
11.04.2018
Accepted: 
11.04.2018
Published: 
21.08.2018