ISSN 1608-4039 (Print)
ISSN 1680-9505 (Online)


For citation:

Ivanov A. V., Chikishev S. A., Bervitskaya O. S., Ichetovkina V. A., Ichetovkin Z. N., Fominykh A. M., Vorotnikov V. A., Bobro M. S., Kuzmin A. V. Application of nickel-cobalt alloy in the composite anode to enhance characteristics of tubular SOFCs. Electrochemical Energetics, 2024, vol. 24, iss. 4, pp. 180-184. DOI: 10.18500/1608-4039-2024-24-4-180-184, EDN: KEZDMX

This is an open access article distributed under the terms of Creative Commons Attribution 4.0 International License (CC-BY 4.0).
Full text:
(downloads: 31)
Language: 
Russian
Heading: 
Article type: 
Article
UDC: 
544.6:621.355
EDN: 
KEZDMX

Application of nickel-cobalt alloy in the composite anode to enhance characteristics of tubular SOFCs

Autors: 
Ivanov Aleksey Vitalievich, Vyatka State University
Chikishev Stepan Andreevich, Vyatka State University
Bervitskaya Olga S., Vyatka State University
Ichetovkina Victoria A., Vyatka State University
Ichetovkin Zakhar Nikolaevich, Vyatka State University
Fominykh Alexander M., Vyatka State University
Vorotnikov Vladimir A., Vyatka State University
Bobro Mark S., Vyatka State University
Kuzmin Anton Valerievich, Vyatka State University
Abstract: 

The electrochemical characteristics of the tubular solid oxide fuel cells (SOFC) and the symmetrical anodic cells with conventional nickel-cermet and modified nickel-cobalt cermet anodes were studied using voltammetry, electrochemical impedance spectroscopy, and distribution of relaxation time analysis. The tubular SOFC with the modified anode exhibited higher power output and demonstrated lower power loss at reduced temperatures, which is attributed to higher electrical conductivity and lower activation energy of the anodic electrode reaction.

Reference: 
  1. Liu Y., Shao Z., Mori T., Jiang S. P. Development of nickel based cermet anode materials in solid oxide fuel cells – Now and future. Materials Reports: Energy, 2021, vol. 1, no. 1, article no. 100003. https://doi.org/10.1016/j.matre.2020.11.002
  2. Shaikh S. P. S., Muchtar A., Somalu M. R. A review on the selection of anode materials for solidoxide fuel cells. Renewable and Sustainable Energy Reviews, 2015, vol. 51, pp. 1–8. https://doi.org/10.1016/j.rser.2015.05.069
  3. Wang Z. R., Qian J. Q., Wang S. R., Cao J. D., Wen T. L. Improvement of anode-supported solid oxide fuel cells. Solid State Ion., 2008, vol. 179, iss. 27– 32, pp. 1593–1596. https://doi.org/10.1016/j.ssi.2008.03.022
  4. Krainova D. A., Saetova N. S., Farlenkov A. S., Khodimchuk A. V., Polyakova I. G., Kuzmin A. V. Long-term stability of SOFC glass sealant under oxidising and reducing atmospheres. Ceram Int., 2021, vol. 47, no. 7, pp. 8973–8979. https://doi.org/10.1016/j.ceramint.2020.12.019
  5. Krainova D. A., Saetova N. S., Polyakova I. G., Farlenkov A. S., Zamyatin D. A., Kuzmin A. V. Behaviour of 54.4SiO2-13.7Na2O-1.7K2O-5.0CaO12.4MgO-0.6Y2O3-11.3Al2O3-0.9B2O3 HT-SOFC glass sealant under oxidising and reducing atmospheres. Ceram Int., 2022, vol. 48, iss. 5, pp. 6124–6130. https://doi.org/10.1016/j.ceramint.2021.11.151
  6. Osinkin D. A. Boosting electrochemical performance of Ni/YSZ electrode through simultaneous injection of nickel and ceria. Int. J. Hydrogen Energy, 2024, vol. 82, pp. 1222–1229. https://doi.org/10.1016/j.ijhydene.2024.08.083
Received: 
14.10.2024
Accepted: 
13.11.2024
Published: 
25.12.2024