By cyclic voltammetry in alkaline solution investigatied electrochemical and electrocatalytic properties of polymeric phthalocyanines and Macroheterocyclic compounds with cobalt. Influence of change of potentials in area from 0,5 to-1,4 B and speeds of scanning from 5 to 100 mV/s on cyclic I-E-curves and redox-transformations of catalysts is studied.